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Gas Permeation and Diffusion in Cross-Linked Poly(ethylene glycol diacrylate)
Abstract
The permeability of cross-linked poly(ethylene glycol diacrylate) (XLPEGDA) to He, H 2, O 2, N 2, CO 2, CH 4, C 2 H 4, C 2 H 6, C 3 H 6, and C 3 H 8 was determined at temperatures ranging from −20 to +45 °C and at fugacities up to approximately 15 atm for some gases. Diffusion coefficients of CO 2 and hydrocarbons were calculated as a function of temperature and local penetrant concentration. The effect of temperature and fugacity on permeability and diffusivity is satisfactorily described using either an activated diffusion model or a free volume-based model.
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Cited by
Transport and structural characteristics of crosslinked poly(ethylene oxide) rubbers
LIN, H., WAGNER, E., SWINNEA, J., FREEMAN, B., PAS, S., HILL, A., KALAKKUNNATH, S., & KALIKA, D. (2006) · Journal of Membrane Science · doi:10.1016/j.memsci.2005.09.040 · Cited by 327
Self-citationModeling of Oxygen-Inhibited Free Radical Photopolymerization in a PDMS Microfluidic Device
Dendukuri, D., Panda, P., Haghgooie, R., Kim, J. M., Hatton, T. A., & Doyle, P. S. (2008) · Macromolecules · doi:10.1021/ma801219w · Cited by 324
Saha, D., Grappe, H. A., Chakraborty, A., & Orkoulas, G. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00745 · Cited by 316
Metadata
- Authors
- Lin, H., & Freeman, B. D.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-04-14
- Volume
- 39
- Issue
- 10
- Pages
- 3568-3580
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1992641283
- Cited by
- 184
- References
- 0
- FWCI
- 19.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lin, H., & Freeman, B. D. (2006). Gas Permeation and Diffusion in Cross-Linked Poly(ethylene glycol diacrylate). Macromolecules. https://doi.org/10.1021/ma051686o
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