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Polymer−Clay Nanocomposite Latex Particles by Inverse Pickering Emulsion Polymerization Stabilized with Hydrophobic Montmorillonite Platelets
Abstract
We present the first surfactant-free inverse emulsion polymerization by using organically modified clay platelets as stabilizers. Colloidally stable inverse Pickering emulsions of aqueous acrylamide (AAm) or 2-hydroxyethyl methacrylate (HEMA) in cyclohexane stabilized by hydrophobic Cloisite 20A (MMT20) were prepared. With both oil-soluble 2,2‘-azobis(isobutyronitrile) (AIBN) and water-soluble 2,2‘-azobis[2-methyl- N -(2-hydroxyethyl)propionamide] (VA-086) as initiators, inverse latexes in the size range of 700−980 nm were successfully obtained. It has been revealed by SEM and cryo-TEM that the latexes were stabilized by hydrophobic clays, as exemplified by the rugged surface of the particles. It was shown from thermogravimetric analysis (TGA) that all the clay platelets were incorporated into the composite particles, and in partially exfoliated state as indicated by X-ray diffraction study.
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Cited by
Emulsions stabilized with solid nanoparticles: Pickering emulsions
Chevalier, Y., & Bolzinger, M.-A. (2013) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2013.02.054 · Cited by 1,765
Self-Healing Polymers and Composites
Blaiszik, B. J., Kramer, S. L. B., Olugebefola, S. C., Moore, J. S., Sottos, N. R., & White, S. R. (2010) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-070909-104532 · Cited by 1,505
Polymer Nanocomposites with Prescribed Morphology: Going beyond Nanoparticle-Filled Polymers
Vaia, R. A., & Maguire, J. F. (2007) · Chemistry of Materials · doi:10.1021/cm062693+ · Cited by 481
Metadata
- Authors
- Voorn, D. J., Ming, W., & van Herk, A. M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-02-23
- Volume
- 39
- Issue
- 6
- Pages
- 2137-2143
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2106492951
- Cited by
- 241
- References
- 0
- FWCI
- 11.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Polymer−Clay Nanocomposite Latex Particles by Inverse Pickering Emulsion Polymerization Stabilized with Hydrophobic Montmorillonite Platelets. https://app.cochat.ai/papers/10.1021/ma052539t
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- Voorn, D. J., Ming, W., & van Herk, A. M. (2006). Polymer−Clay Nanocomposite Latex Particles by Inverse Pickering Emulsion Polymerization Stabilized with Hydrophobic Montmorillonite Platelets. Macromolecules. https://doi.org/10.1021/ma052539t
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