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Cited by 270

The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.

Ring-Opening Polymerization of Lactides Initiated by Zinc Alkoxides Derived from NNO-Tridentate Ligands

Chen, Hsuan-Ying, Tang, Hui-Yi, Lin, Chu-Chieh·2006·Macromolecules

Abstract

A new series of dinuclear zinc complexes of the types [LZnEt] 2 and [LZn(μ-OBn)] 2 (where L = NNO-tridentate Schiff base ligand) have been prepared. The activities of zinc alkoxides, [LZn(μ-OBn)] 2, toward the ring-opening polymerization of l -lactide have been investigated. Experimental results indicate that the reactivity of [LZn(μ-OBn)] 2 was dramatically affected by both the electronic and steric effect of the substituents on the Schiff base. The polymerization kinetics using [L 1 Zn(μ-OBn)] 2 ( 2a ) as an initiator were also studied, and the experimental results reveal that the rate of reaction is first-order, which depends on both [LA] and [L 1 Zn(μ-OBn)] 2 . Furthermore, the heterotactic PLA with Pr up to 91% can be achieved by initiating of [L 5 Zn(μ-OBn)] 2 in CH 2 Cl 2 at −55 °C.

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Metadata

Authors
Chen, H.-Y., Tang, H.-Y., & Lin, C.-C.
Venue
Macromolecules
Published
2006-05-01
Volume
39
Issue
11
Pages
3745-3752
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W1985269719
Cited by
270
References
10
FWCI
6.81
Type
journal article
Language
en
Open access
closed

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