Immortal Polymerization of epsilon-caprolactone, initiated by aluminum porphyrin in the presence of alcohol
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVarticleNEXTImmortal polymerization of .epsilon.-caprolactone initiated by aluminum porphyrin in the presence of alcoholMasato Endo, Takuzo Aida, and Shohei InoueCite this: Macromolecules 1987, 20, 12, 2982–2988Publication Date (Print):May 1, 1987Publication History Published online1 May 1987Published inissue 1 May 1987https://pubs.acs.org/doi/10.1021/ma00178a005https://doi.org/10.1021/ma00178a005research-articleACS PublicationsCopyright © 1987 American Chemical SocietyRequest reuse permissionsArticle Views1028Altmetric-Citations196LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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Initiators based on porphyrin complexes or related structures based on Al, Zn, Y, Lu, In have been used for polymerization of oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others.
“The initiators based on porphyrin complexes or complexes with related structures based on Al, Zn, Y, Lu, In have been used for the polymerization of e.g., oxiranes, thiiranes, lactones, lactides, cyclic carbonates and others [147,149 -156].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [155]
Cites
A simplified synthesis for meso-tetraphenylporphine
Adler, A. D., Longo, F. R., Finarelli, J. D., Goldmacher, J. E., Assour, J. M., & Korsakoff, L. (1967) · The Journal of Organic Chemistry · doi:10.1021/jo01288a053 · Cited by 2,696 · see citing works
Asano, S., Aida, T., & Inoue, S. (1985) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39850001148 · Cited by 128 · see citing works
Self-citationHamitou, A., Ouhadi, T., Jérôme, R., & Teyssié, P. (1977) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1977.170150409 · Cited by 95 · see citing works
Yasuda, T., Aida, T., & Inoue, S. (1983) · Macromolecules · doi:10.1021/ma00245a020 · Cited by 63 · see citing works
Self-citationReaction of Carbon Dioxide with Tetraphenylporphinatoaluminium Ethyl in Visible Light
Inoue, S., & Takeda, N. (1977) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.50.984 · Cited by 46 · see citing works
Self-citationYasuda, T., Aida, T., & Inoue, S. (1986) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.59.3931 · Cited by 25 · see citing works
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Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates
Ajellal, N., Carpentier, J.-F., Guillaume, C., Guillaume, S. M., Helou, M., Poirier, V., Sarazin, Y., & Trifonov, A. (2010) · Dalton Transactions · doi:10.1039/c001226b · Cited by 494 · see citing works
Ring-Opening Polymerization—An Introductory Review
Nuyken, O., & Pask, S. (2013) · Polymers · doi:10.3390/polym5020361 · Cited by 456 · see citing works
“carbonates and others [147,149–156].”
Metal catalysts for ε-caprolactone polymerisation
Arbaoui, A., & Redshaw, C. (2010) · Polymer Chemistry · doi:10.1039/b9py00334g · Cited by 383 · see citing works
Jeon, O., Lee, S.-H., Kim, S. H., Lee, Y. M., & Kim, Y. H. (2003) · Macromolecules · doi:10.1021/ma034006v · Cited by 168 · see citing works
Chen, H.-Y., Huang, B.-H., & Lin, C.-C. (2005) · Macromolecules · doi:10.1021/ma050672f · Cited by 166 · see citing works
Shueh, M.-L., Wang, Y.-S., Huang, B.-H., Kuo, C.-Y., & Lin, C.-C. (2004) · Macromolecules · doi:10.1021/ma049778l · Cited by 127 · see citing works
Duan, R., Hu, C., Li, X., Pang, X., Sun, Z., Chen, X., & Wang, X. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01766 · Cited by 96 · see citing works
Nalampang, K., Molloy, R., & Punyodom, W. (2007) · Polymers for Advanced Technologies · doi:10.1002/pat.880 · Cited by 59 · see citing works
Ma, W.-A., Wang, L., & Wang, Z.-X. (2011) · Dalton Transactions · doi:10.1039/c0dt01713b · Cited by 29 · see citing works
Valente, A., Zinck, P., Mortreux, A., Visseaux, M., Mendes, P. J. G., Silva, T. J. L., & Garcia, M. H. (2011) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/j.molcata.2011.06.015 · Cited by 9 · see citing works
- Authors
- Endo, M., Aida, T., & Inoue, S.
- ORCID
- Aida, Takuzo
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1987-05-01
- Volume
- 20
- Issue
- 12
- Pages
- 2982-2988
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2053426792
- Cited by
- 209
- References
- 6
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 1 · 2023: 1 · 2022: 4 · 2021: 3 · 2020: 3 · 2019: 3 · 2017: 3 · 2016: 4 · 2015: 7 · 2013: 5 · 2012: 12
- FWCI
- 2.71
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Keywords
- ε-caprolactone, aluminum porphyrin, ring-opening polymerization, porphyrin catalysts, polymerization initiation
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