The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Exploration, Optimization, and Application of Supramolecular Thiourea−Amine Catalysts for the Synthesis of Lactide (Co)polymers
Abstract
The structural flexibility and efficacy of thiourea−amine catalysts for the supramolecular activation and ring-opening polymerization (ROP) of lactide are described. The nature of the hydrogen bonding group and its strength as well as the steric congestion have been altered, leading to shorter polymerization times, better control, and pathways to influence the stereochemistry of the resulting polymer. The tolerance to functionality and the mild conditions of the ROP mechanism allow for block copolymer synthesis by combination of nitroxide-mediated polymerization as well as reversible addition fragmentation and chain transfer polymerization using dual-headed initiators. Tandem hydrogen bond activation to organocatalyze ROP of lactide is an effective, versatile means to generate polymers with predictable molecular weights, narrow polydispersities, control of microstructure and a variety of complex architectures and block copolymers.
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Citations
Cites
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257
Polymerization of Lactide with Zinc and Magnesium β-Diiminate Complexes: Stereocontrol and Mechanism
Chamberlain, B. M., Cheng, M., Moore, D. R., Ovitt, T. M., Lobkovsky, E. B., & Coates, G. W. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003851f · Cited by 1,207
Ovitt, T. M., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012052+ · Cited by 713
Cited by
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Self-citationNitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Organocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Self-citationBiocompatible Initiators for Lactide Polymerization
Platel, R., Hodgson, L., & Williams, C. (2008) · Polymer Reviews · doi:10.1080/15583720701834166 · Cited by 706
Makiguchi, K., Satoh, T., & Kakuchi, T. (2011) · Macromolecules · doi:10.1021/ma200043x · Cited by 338
Metadata
- Authors
- Pratt, R. C., Lohmeijer, B. G. G., Long, D. A., Lundberg, P. N. P., Dove, A. P., Li, H., Wade, C. G., Waymouth, R. M., & Hedrick, J. L.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-10-18
- Volume
- 39
- Issue
- 23
- Pages
- 7863-7871
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2070523657
- Cited by
- 419
- References
- 3
- FWCI
- 4.71
- Type
- journal article
- Language
- en
- Open access
- closed
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