The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Block Copolymers for Fuel Cells
Abstract
Ion-containing block copolymers hold promise as next-generation proton exchange membranes in hydrogen and methanol fuel cells. These materials’ self-assembled ordered nanostructures facilitate proton transport over a wide range of conditions, a requirement for robust fuel cell performance. In this perspective, we will present an overview of the morphology and transport properties of ion-containing block copolymers that have been studied to gain insight into the fundamental behavior of these materials and, in some cases, are targeted toward applications in fuel cells and other electrochemical devices. We will discuss the challenges associated with predicting and obtaining well-ordered morphologies in block copolymers with high ion content, particularly those with chemistries that can withstand the chemical and mechanical stresses of the fuel cell, such as aromatic backbone block copolymers. New opportunities for ion-containing block copolymers in alkaline membrane fuel cells will also be reviewed.
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Cites
On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells
Kreuer, K. D. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00632-3 · Cited by 2,969
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Parallel cylindrical water nanochannels in Nafion fuel-cell membranes
Schmidt-Rohr, K., & Chen, Q. (2008) · Nature Materials · doi:10.1038/nmat2074 · Cited by 1,371
Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes
Zawodzinski, T. A., Neeman, M., Sillerud, L. O., & Gottesfeld, S. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100168a060 · Cited by 987
Pervaporation membranes in direct methanol fuel cells
Pivovar, B. S., Wang, Y., & Cussler, E. L. (1999) · Journal of Membrane Science · doi:10.1016/s0376-7388(98)00264-6 · Cited by 403
Cited by
New Insights into Perfluorinated Sulfonic-Acid Ionomers
Kusoglu, A., & Weber, A. Z. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00159 · Cited by 2,432
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Self-citationNew roads and challenges for fuel cells in heavy-duty transportation
Cullen, D. A., Neyerlin, K. C., Ahluwalia, R. K., Mukundan, R., More, K. L., Borup, R. L., Weber, A. Z., Myers, D. J., & Kusoglu, A. (2021) · Nature Energy · doi:10.1038/s41560-021-00775-z · Cited by 1,277
Hallinan, D. T., & Balsara, N. P. (2013) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-071312-121705 · Cited by 853
50th Anniversary Perspective: Block Polymers—Pure Potential
Bates, C. M., & Bates, F. S. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02355 · Cited by 788
Metadata
- Authors
- Elabd, Y. A., & Hickner, M. A.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-30
- Volume
- 44
- Issue
- 1
- Pages
- 1-11
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2063277637
- Cited by
- 518
- References
- 5
- FWCI
- 33.14
- Type
- journal article
- Language
- en
- Open access
- closed
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