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High Surface Area Conjugated Microporous Polymers: The Importance of Reaction Solvent Choice
Abstract
The choice of reaction solvent has a major influence on the surface area and pore volume in conjugated microporous polymer (CMP) networks synthesized by Sonogashira−Hagihara palladium-catalyzed cross-coupling chemistry of aromatic dibromo monomers with 1,3,5-triethynylbenzene. Four solvents were evaluated for these reactions: N,N -dimethylformamide (DMF), 1,4-dioxane, tetrahydrofuran (THF), and toluene. Networks synthesized in DMF tend to exhibit the highest surface areas (up to 1260 m 2 /g), whereas those synthesized in toluene have on average significantly lower surface areas and pore volumes. By judicious choice of reaction solvent, microporous materials can be prepared which combine high surface area with a variety of functional groups of interest in applications such as gas storage, molecular separations, and catalysis.
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Cites
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Cited by
Design and Preparation of Porous Polymers
Wu, D., Xu, F., Sun, B., Fu, R., He, H., & Matyjaszewski, K. (2012) · Chemical Reviews · doi:10.1021/cr200440z · Cited by 1,748
Nanoporous organic polymer networks
Dawson, R., Cooper, A. I., & Adams, D. J. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.09.002 · Cited by 1,114
Self-citationIodine capture in porous organic polymers and metal–organic frameworks materials
Xie, W., Cui, D., Zhang, S.-R., Xu, Y.-H., & Jiang, D.-L. (2019) · Materials Horizons · doi:10.1039/c8mh01656a · Cited by 622
Porous Organic Polymers for Post‐Combustion Carbon Capture
Zou, L., Sun, Y., Che, S., Yang, X., Wang, X., Bosch, M., Wang, Q., Li, H., Smith, M., Yuan, S., et al. (2017) · Advanced Materials · doi:10.1002/adma.201700229 · Cited by 432
Porous covalent–organic materials: synthesis, clean energy application and design
Xiang, Z., & Cao, D. (2013) · J. Mater. Chem. A · doi:10.1039/c2ta00063f · Cited by 351
Metadata
- Authors
- Dawson, R., Laybourn, A., Khimyak, Y. Z., Adams, D. J., & Cooper, A. I.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-24
- Volume
- 43
- Issue
- 20
- Pages
- 8524-8530
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2022306081
- Cited by
- 219
- References
- 1
- FWCI
- 8.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dawson, R., Laybourn, A., Khimyak, Y. Z., Adams, D. J., & Cooper, A. I. (2010). High Surface Area Conjugated Microporous Polymers: The Importance of Reaction Solvent Choice. Macromolecules. https://doi.org/10.1021/ma101541h
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