Toward Well-Controlled ab Initio RAFT Emulsion Polymerization of Styrene Mediated by 2-(((Dodecylsulfanyl)carbonothioyl)sulfanyl)propanoic Acid

Luo, Yingwu; Wang, Xiaoguang; Li, Bo-Geng; Zhu, Shiping

doi:10.1021/ma102378w

Cited by 70Advanced Polymer Synthesis and CharacterizationPickering emulsions and particle stabilizationSurfactants and Colloidal Systems

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Toward Well-Controlled ab Initio RAFT Emulsion Polymerization of Styrene Mediated by 2-(((Dodecylsulfanyl)carbonothioyl)sulfanyl)propanoic Acid

Luo, Yingwu, Wang, Xiaoguang, Li, Bo-Geng, Zhu, Shiping·2011·Macromolecules

DOI 10.1021/ma102378w

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Abstract

Reversible addition−fragmentation chain transfer (RAFT) ab initio emulsion polymerization of styrene mediated by 2-(((dodecylsulfanyl) carbonothioyl) sulfanyl) propanoic acid was investigated with sodium dodecyl sulfate (SDS), poly(acrylic acid) 29 - b -polystyrene 5 trithiocarbonate macro-RAFT agent (PAA 29 -PSt 5 -RAFT), and poly(acrylic acid) 29 - b -polystyrene 5 diblock co-oligomer (PAA 29 -PSt 5 ) as the surfactant, respectively. Polystyrene latex having controlled molecular weight, relatively low PD and narrow particle size distribution was obtained by postneutralizing PAA 29 -PSt 5 -RAFT and PAA 29 -PSt 5 . This result was in agreement with the superswelling hypothesis that superswollen oligomer-containing particles caused the colloidal instability in the early stage of RAFT emulsion polymerization with SDS as surfactant. The successes of PAA 29 -PSt 5 -RAFT and PAA 29 -PSt 5 were due to the high interfacial tensions of the styrene/water/surfactant systems that suppressed the superswelling and thus improved the colloidal instability. A majority of the initial RAFT molecules appeared to be converted at a low monomer conversion due to the inhibition period.

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Zhu et al. employed an amphiphilic oligomer, PAA-b-PS trithiocarbonate, as both surfactant and RAFT agent to polymerize styrene.
“Zhu et al. employed an amphiphilic oligomer, poly(acrylic acid-b-styrene) trithiocarbonate, as both surfactant and RAFT agent to polymerize styrene.”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [35]
This macro-RAFT agent was capable of enhancing colloidal stability and, as a result, the polymerization was successful.
“This macro-RAFT agent was capable of enhancing the colloidal stability and, as a result, the polymerization was successful [34,35].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [35]

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Authors: Luo, Y., Wang, X., Li, B.-G., & Zhu, S.
Affiliations: State Key Laboratory of Chemical Engineering (CN)
McMaster University (CA)
Corresponding author: Luo, Yingwu
Li, Bo-Geng
Zhu, Shiping
ORCID: Luo, Yingwu
Wang, Xiaoguang
Li, Bo-Geng
Zhu, Shiping
Venue: Macromolecules
Publisher: American Chemical Society (ACS)
Published: 2010-12-30
Volume: 44
Issue: 2
Pages: 221-229
ISSN: 0024-9297 (ISSN-L)
1520-5835
DOI: 10.1021/ma102378w
OpenAlex: W2002332117
Cited by: 70
References: 66
Citations by year: 2026: 2 · 2025: 2 · 2024: 1 · 2023: 2 · 2022: 2 · 2021: 4 · 2020: 2 · 2019: 4 · 2018: 7 · 2017: 4 · 2016: 7 · 2015: 4 · 2014: 5 · 2013: 8 · 2012: 9
FWCI: 3.80
Type: journal article
Language: en
Open access: closed
Locations: Macromolecules (publishedVersion)
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Materials Science › Materials Chemistry › Pickering emulsions and particle stabilization
Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Surfactants and Colloidal Systems
Keywords: RAFT emulsion polymerization, styrene, sodium dodecyl sulfate, polystyrene latex, colloidal instability, interfacial tension, molecular weight control, particle size distribution

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Toward Well-Controlled ab Initio RAFT Emulsion Polymerization of Styrene Mediated by 2-(((Dodecylsulfanyl)carbonothioyl)sulfanyl)propanoic Acid

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