The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Effect of Architecture on the Phase Behavior of AB-Type Block Copolymer Melts
Abstract
Equilibrium phase diagrams are calculated for a selection of two-component block copolymer architectures using self-consistent field theory (SCFT). The topology of the phase diagrams is relatively unaffected by differences in architecture, but the phase boundaries shift significantly in composition. The shifts are consistent with the decomposition of architectures into constituent units as proposed by Gido and co-workers, but there are significant quantitative deviations from this principle in the intermediate-segregation regime. Although the complex phase windows continue to be dominated by the gyroid (G) phase, the regions of the newly discovered Fddd (O 70 ) phase become appreciable for certain architectures and the perforated-lamellar (PL) phase becomes stable when the complex phase windows shift toward high compositional asymmetry.
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Citations
Cites
Block Copolymers—Designer Soft Materials
Bates, F. S., & Fredrickson, G. H. (1999) · Physics Today · doi:10.1063/1.882522 · Cited by 3,219
Unifying Weak- and Strong-Segregation Block Copolymer Theories
Matsen, M. W., & Bates, F. S. (1996) · Macromolecules · doi:10.1021/ma951138i · Cited by 1,839
Self-citationStable and unstable phases of a diblock copolymer melt
Matsen, M. W., & Schick, M. (1994) · Physical Review Letters · doi:10.1103/physrevlett.72.2660 · Cited by 1,417
Self-citationThe Equilibrium Theory of Inhomogeneous Polymers
Fredrickson, G. (2005) · doi:10.1093/acprof:oso/9780198567295.001.0001 · Cited by 1,186
Theory of inhomogeneous polymers: Fundamentals of the Gaussian random-walk model
Helfand, E. (1975) · The Journal of Chemical Physics · doi:10.1063/1.430517 · Cited by 591
Origins of complex self-assembly in block copolymers
Matsen, M. W., & Bates, F. S. (1996) · Macromolecules · doi:10.1021/ma960744q · Cited by 578
Self-citationCombinatorial Screening of Complex Block Copolymer Assembly with Self-Consistent Field Theory
Drolet, F., & Fredrickson, G. H. (1999) · Physical Review Letters · doi:10.1103/physrevlett.83.4317 · Cited by 542
Phase Behavior of Block Copolymer/Homopolymer Blends
Matsen, M. W. (1995) · Macromolecules · doi:10.1021/ma00121a011 · Cited by 483
Self-citationEquilibrium behavior of symmetric ABA triblock copolymer melts
Matsen, M. W., & Thompson, R. B. (1999) · The Journal of Chemical Physics · doi:10.1063/1.480006 · Cited by 456
Self-citationFluctuations, conformational asymmetry and block copolymer phase behaviour
Bates, F. S., Schulz, M. F., Khandpur, A. K., Förster, S., Rosedale, J. H., Almdal, K., & Mortensen, K. (1994) · Faraday Discuss. · doi:10.1039/fd9949800007 · Cited by 435
Cited by
Han, L., & Che, S. (2018) · Advanced Materials · doi:10.1002/adma.201705708 · Cited by 624
Block copolymer electrolytes for rechargeable lithium batteries
Young, W., Kuan, W., & Epps (2014) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23404 · Cited by 417
Aliphatic Polyester Block Polymer Design
Schneiderman, D. K., & Hillmyer, M. A. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b00211 · Cited by 290
Martello, M. T., Schneiderman, D. K., & Hillmyer, M. A. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc500412a · Cited by 120
Poly(lactide)-block-poly(ε-caprolactone-co-ε-decalactone)-block-poly(lactide) copolymer elastomers
Schneiderman, D. K., Hill, E. M., Martello, M. T., & Hillmyer, M. A. (2015) · Polymer Chemistry · doi:10.1039/c5py00202h · Cited by 101
Metadata
- Authors
- Matsen, M. W.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-07
- Volume
- 45
- Issue
- 4
- Pages
- 2161-2165
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1966315732
- Cited by
- 507
- References
- 49
- FWCI
- 9.85
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
