The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Polymerization-Induced Self-Assembly: From Soluble Macromolecules to Block Copolymer Nano-Objects in One Step
Abstract
This Perspective describes the recent developments of polymerization-induced self-assembly of amphiphilic block copolymers based on controlled/living free-radical polymerization (CRP) in water. This method relies on the use of a hydrophilic living polymer precursor prepared via CRP that is extended with a hydrophobic second block in an aqueous environment. The process thus leads to amphiphilic block copolymers that self-assemble in situ into self-stabilized nano-objects in the frame of an emulsion or dispersion polymerization process. Depending on the nature and the structure of the so-formed copolymer, not only spherical particles can be achieved but also all morphologies that can be found in the phase diagram of an amphiphilic block copolymer in a selective solvent. This paper focuses mainly on aqueous emulsion or dispersion polymerization and gives an overview of the CRP techniques used, the general conditions, and the morphologies obtained.
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Cites
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Blanazs, A., Armes, S. P., & Ryan, A. J. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800713 · Cited by 1,500
Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems
Qiu, J., Charleux, B., & Matyjaszewski, K. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00033-8 · Cited by 595
Self-citationSugihara, S., Sugihara (nee Nishikawa), K., Armes, S. P., Ahmad, H., & Lewis, A. L. (2010) · Macromolecules · doi:10.1021/ma101136v · Cited by 72
Cited by
Corrigan, N., Jung, K., Moad, G., Hawker, C. J., Matyjaszewski, K., & Boyer, C. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101311 · Cited by 981
Derry, M. J., Fielding, L. A., & Armes, S. P. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2015.10.002 · Cited by 631
RAFT‐Mediated Polymerization‐Induced Self‐Assembly
D'Agosto, F., Rieger, J., & Lansalot, M. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201911758 · Cited by 592
Self-citationExpanding the Scope of RAFT Polymerization: Recent Advances and New Horizons
Hill, M. R., Carmean, R. N., & Sumerlin, B. S. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00342 · Cited by 494
Controlled/Living Radical Polymerization in Dispersed Systems: An Update
Zetterlund, P. B., Thickett, S. C., Perrier, S., Bourgeat-Lami, E., & Lansalot, M. (2015) · Chemical Reviews · doi:10.1021/cr500625k · Cited by 485
Metadata
- Authors
- Charleux, B., Delaittre, G., Rieger, J., & D’Agosto, F.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-25
- Volume
- 45
- Issue
- 17
- Pages
- 6753-6765
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2320243037
- Cited by
- 812
- References
- 4
- FWCI
- 22.31
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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