The DOI matches its Crossref record; 90 of the 90 references it cites were found in a registry or an index.
Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons
Abstract
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer chemistry over the past two decades, thus laying the groundwork for the synthesis of complex macromolecules and enabling the preparation of previously inaccessible materials. Reversible addition-fragmentation chain transfer (RAFT) polymerization has emerged as one of the most promising techniques because of its functional group tolerance, applicability to a wide range of vinyl monomers, and its nondemanding experimental conditions. However, despite the promise and clearly demonstrated utility of RAFT, limitations of the method sometimes still exist, including the occasional need for extended polymerization times, limited access to high molecular weight polymers, low “livingness” due to unavoidable radical termination events, etc. This Perspective focuses on recent advances that have been specifically designed to address many of these perceived limitations to reinforce the promise of RAFT for the synthesis of complex and well-defined polymers under facile conditions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Chiefari, J., Chong, Y. K. (., Ercole, F., Krstina, J., Jeffery, J., Le, T. P. T., Mayadunne, R. T. A., Meijs, G. F., Moad, C. L., Moad, G., et al. (1998) · Macromolecules · doi:10.1021/ma9804951 · Cited by 5,147
Controlled Microwave Heating in Modern Organic Synthesis
Kappe, C. O. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200400655 · Cited by 3,607
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
Matyjaszewski, K. (2012) · Macromolecules · doi:10.1021/ma3001719 · Cited by 2,606
Living Radical Polymerization by the RAFT Process – A Third Update
Moad, G., Rizzardo, E., & Thang, S. H. (2012) · Australian Journal of Chemistry · doi:10.1071/ch12295 · Cited by 1,698
Handbook of Radical Polymerization
(2002) · Wiley eBooks · doi:10.1002/0471220450 · Cited by 1,595
Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials
Iha, R. K., Wooley, K. L., Nyström, A. M., Burke, D. J., Kade, M. J., & Hawker, C. J. (2009) · Chemical Reviews · doi:10.1021/cr900138t · Cited by 1,468
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Lutz, J.-F., Ouchi, M., Liu, D. R., & Sawamoto, M. (2013) · Science · doi:10.1126/science.1238149 · Cited by 1,381
Perrier, S., & Takolpuckdee, P. (2005) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20986 · Cited by 1,130
Warren, N. J., & Armes, S. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502843f · Cited by 1,107
Cited by
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules
Grubbs, R. B., & Grubbs, R. H. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01440 · Cited by 396
Tritschler, U., Pearce, S., Gwyther, J., Whittell, G. R., & Manners, I. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02767 · Cited by 375
Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization
Carmean, R. N., Becker, T. E., Sims, M. B., & Sumerlin, B. S. (2017) · Chem · doi:10.1016/j.chempr.2016.12.007 · Cited by 292
Self-citationMcKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
Metadata
- Authors
- Hill, M. R., Carmean, R. N., & Sumerlin, B. S.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-28
- Volume
- 48
- Issue
- 16
- Pages
- 5459-5469
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2338096747
- Cited by
- 494
- References
- 90
- FWCI
- 26.67
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons. https://app.cochat.ai/papers/10.1021/acs.macromol.5b00342
- The paper
- Hill, M. R., Carmean, R. N., & Sumerlin, B. S. (2015). Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons. Macromolecules. https://doi.org/10.1021/acs.macromol.5b00342
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
