The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst
Abstract
Well-controlled polymerization of methyl methacrylate at 35 °C was achieved by photochemically mediated atom transfer radical polymerization using a copper catalyst concentration as low as 50–100 ppm. Irradiation at λ > 350 nm provided both a reduction of initially added copper(II) catalyst complexed with either PMDETA or TPMA ligand to a copper(I) activator and a sufficient rate of polymerization. Poly(methyl methacrylate) with a narrow dispersity and predictable molar mass was obtained when an initiator, such as 2-bromopropionitrile, was used. Successful chain-extension polymerization confirmed the living character of the photopolymerization system.
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Citations
Cites
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Cited by
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Macromolecular Engineering by Atom Transfer Radical Polymerization
Matyjaszewski, K., & Tsarevsky, N. V. (2014) · Journal of the American Chemical Society · doi:10.1021/ja408069v · Cited by 1,159
Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst
Konkolewicz, D., Schröder, K., Buback, J., Bernhard, S., & Matyjaszewski, K. (2012) · ACS Macro Letters · doi:10.1021/mz300457e · Cited by 593
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update
Parkatzidis, K., Wang, H. S., Truong, N. P., & Anastasaki, A. (2020) · Chem · doi:10.1016/j.chempr.2020.06.014 · Cited by 512
Miyake, G. M., & Theriot, J. C. (2014) · Macromolecules · doi:10.1021/ma502044f · Cited by 351
Metadata
- Authors
- Mosnáček, J., & Ilčíková, M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-07-19
- Volume
- 45
- Issue
- 15
- Pages
- 5859-5865
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2332298298
- Cited by
- 241
- References
- 1
- FWCI
- 12.98
- Type
- journal article
- Language
- en
- Open access
- closed
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