The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide The generation of carbon-centered radicals from alkyl bromides through an oxidative quenching pathway using perylene as an organic visible-light photocatalyst is described. This methodology is used to initiate the radical polymerization of methyl methacrylate and other functionalized vinyl monomers. The polymers possess bromide chain-end groups that can be used to reinitiate polymerization to produce block copolymers. Control over the polymerization propagation can be achieved through pulsed light sequences while the ability to use natural sunlight to promote carbon–carbon bond formation produces polymers with dispersity as low as 1.29.
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Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Pearson, R. M., Lim, C.-H., McCarthy, B. G., Musgrave, C. B., & Miyake, G. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08068 · Cited by 339
Self-citationWu, C., Corrigan, N., Lim, C.-H., Liu, W., Miyake, G., & Boyer, C. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00409 · Cited by 259
Self-citationBlock copolymer synthesis in one shot: Concurrent metal-free atrp and rop processes under sunlight
Aydogan, C., Kutahya, C., Allushi, A., Yilmaz, G., & Yagci, Y. (2017) · Polymer Chemistry · doi:10.1039/c7py00069c · Cited by 78
Metadata
- Authors
- Miyake, G. M., & Theriot, J. C.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-18
- Volume
- 47
- Issue
- 23
- Pages
- 8255-8261
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2090487791
- Cited by
- 351
- References
- 3
- FWCI
- 14.45
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Miyake, G. M., & Theriot, J. C. (2014). Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light. Macromolecules. https://doi.org/10.1021/ma502044f
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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