The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
From Petrochemical Polyurethanes to Biobased Polyhydroxyurethanes
Open accessAbstract
From a green and sustainable chemistry standpoint, the current challenge in the polyurethane’s industry is to switch from petrobased polyurethanes (PUs) to biobased polyhydroxyurethanes (PHUs). This review describes the main alternative strategies being developed with a focus on PHUs from vegetable oils and derivatives. The substitution of petrobased polyols by natural oil based polyols was the first route to biobased PUs to be developed. The second strategy involves synthesis without the need of harmful isocyanate by the nucleophilic polyaddition of polyamines to polycyclic carbonates. The technological barrier to the synthesis of biobased cyclic carbonates could be overcome by the chemical transformation of epoxidized vegetable oils or by the use of glycerine carbonate-based intermediates. New families of biobased PHUs with a lower environmental footprint could be generated.
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Cites
Plant oil renewable resources as green alternatives in polymer science
Meier, M. A. R., Metzger, J. O., & Schubert, U. S. (2007) · Chemical Society Reviews · doi:10.1039/b703294c · Cited by 1,487
Shaikh, A.-A. G., & Sivaram, S. (1996) · Chemical Reviews · doi:10.1021/cr950067i · Cited by 1,381
Reactive Applications of Cyclic Alkylene Carbonates
Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784
Cited by
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Recycling of polyurethanes from laboratory to industry, a journey towards the sustainability
Simón, D., Borreguero, A. M., de Lucas, A., & Rodríguez, J. F. (2018) · Waste Management · doi:10.1016/j.wasman.2018.03.041 · Cited by 405
Blattmann, H., Fleischer, M., Bähr, M., & Mülhaupt, R. (2014) · Macromolecular Rapid Communications · doi:10.1002/marc.201400209 · Cited by 339
Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics
Maisonneuve, L., Lebarbé, T., Grau, E., & Cramail, H. (2013) · Polymer Chemistry · doi:10.1039/c3py00791j · Cited by 220
Thermal Degradation Effects on Polyurethanes and Their Nanocomposites
Navarro‐Baena, I., Arrieta, M. P., Mujica‐Garcia, A., Sessini, V., Lopez, D., Kenny, J. M., & Peponi, L. (2015) · Reactions and Mechanisms in Thermal Analysis of Advanced Materials · doi:10.1002/9781119117711.ch7 · Cited by 8
Metadata
- Authors
- Nohra, B., Candy, L., Blanco, J.-F., Guerin, C., Raoul, Y., & Mouloungui, Z.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-16
- Volume
- 46
- Issue
- 10
- Pages
- 3771-3792
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2054186950
- Cited by
- 395
- References
- 3
- FWCI
- 11.26
- Type
- journal article
- Language
- en
- Open access
- green
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- Nohra, B., Candy, L., Blanco, J.-F., Guerin, C., Raoul, Y., & Mouloungui, Z. (2013). From Petrochemical Polyurethanes to Biobased Polyhydroxyurethanes. Macromolecules. https://doi.org/10.1021/ma400197c
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