Cited by 220biodegradable polymer synthesis and propertiesPolymer composites and self-healingPolymer Science and PVC

Structure–properties relationship of fatty acid-based thermoplastics as synthetic polymer mimics

Open access
Maisonneuve, Lise, Lebarbé, Thomas, Grau, Etienne, Cramail, Henri·2013·Polymer Chemistry

Abstract

Nowadays the use of vegetable oils as polymer precursors is the subject of growing interest in the academic and industrial communities. Many synthetic pathways can be pursued from natural vegetable oils to yield different functionalized derivatives – also called synthons – and polymers, such as polyesters, polyurethanes, polyamides, etc. Herein, we widely overview recent progress in the preparation of vegetable oil-based thermoplastic polymers and, more precisely, thermoplastic polyesters and polyurethanes. Extra focus is also placed on the synthesis sustainability of these polymeric materials via atom efficient techniques, “green” catalyses and processes. The achievable bio-sourced polymers cover a wide range of thermo-mechanical properties that can respond to most of the current applications of synthetic polymers.

Integrity signals

Registry

Crossref · 10.1039/c3py00791j

Cites

238 of 238 references verified0 citation errors · 0 not checkable

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  • Fatty acids obtained from transesterification of plant oils have been a long-standing biofeedstock for polymer production.

    “Fatty acids obtained from transesterification of plant oils have been a long-standing biofeedstock for polymer production.25,98”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [98]

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Authors
Maisonneuve, L., Lebarbé, T., Grau, E., & Cramail, H.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
Cramail, Henri
Venue
Polymer Chemistry
Published
2013
Volume
4
Issue
22
Pages
5472
ISSN
  • 1759-9954 (ISSN-L)
  • 1759-9962
OpenAlex
W2025548396
Cited by
220
References
240
Citations by year
2026: 7 · 2025: 8 · 2024: 11 · 2023: 8 · 2022: 12 · 2021: 17 · 2020: 17 · 2019: 19 · 2018: 22 · 2017: 18 · 2016: 26 · 2015: 22 · 2014: 29 · 2013: 4
FWCI
10.30
Type
journal article
Language
en
Open access
Licence
other-oa
Locations
  • Polymer Chemistry (publishedVersion)
  • HAL (submittedVersion, other-oa)
  • Oskar-Bordeaux (Universite de Bordeaux) (submittedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Science and PVC
Keywords
thermoplastic polyesters, thermoplastic polyurethane, structure-property relationships, bio-based polymers, atom economy, green catalysis, thermomechanical properties

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