The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide The generation of carbon-centered radicals from alkyl bromides through an oxidative quenching pathway using perylene as an organic visible-light photocatalyst is described. This methodology is used to initiate the radical polymerization of methyl methacrylate and other functionalized vinyl monomers. The polymers possess bromide chain-end groups that can be used to reinitiate polymerization to produce block copolymers. Control over the polymerization propagation can be achieved through pulsed light sequences while the ability to use natural sunlight to promote carbon–carbon bond formation produces polymers with dispersity as low as 1.29.
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Cites
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Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Photoredox catalysis using infrared light via triplet fusion upconversion
Ravetz, B. D., Pun, A. B., Churchill, E. M., Congreve, D. N., Rovis, T., & Campos, L. M. (2019) · Nature · doi:10.1038/s41586-018-0835-2 · Cited by 676
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Pearson, R. M., Lim, C.-H., McCarthy, B. G., Musgrave, C. B., & Miyake, G. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08068 · Cited by 339
Self-citationXu, J., Shanmugam, S., Fu, C., Aguey-Zinsou, K.-F., & Boyer, C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12408 · Cited by 313
Wu, C., Corrigan, N., Lim, C.-H., Liu, W., Miyake, G., & Boyer, C. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00409 · Cited by 259
Self-citationBlock copolymer synthesis in one shot: Concurrent metal-free atrp and rop processes under sunlight
Aydogan, C., Kutahya, C., Allushi, A., Yilmaz, G., & Yagci, Y. (2017) · Polymer Chemistry · doi:10.1039/c7py00069c · Cited by 78
Metadata
- Authors
- Miyake, G. M., & Theriot, J. C.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-18
- Volume
- 47
- Issue
- 23
- Pages
- 8255-8261
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2090487791
- Cited by
- 351
- References
- 52
- FWCI
- 14.45
- Type
- journal article
- Language
- en
- Open access
- hybrid
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