Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

Aydogan, Cansu; Kutahya, Ceren; Allushi, Andrit; Yilmaz, Gorkem; Yagci, Yusuf

doi:10.1039/c7py00069c

Cited by 78Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPhotopolymerization techniques and applications

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Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

Aydogan, Cansu, Kutahya, Ceren, Allushi, Andrit, Yilmaz, Gorkem, Yagci, Yusuf·2017·Polymer Chemistry

DOI 10.1039/c7py00069c

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Abstract

A completely metal-free strategy was developed by combining Atom Transfer Radical Polymerization (ATRP) and Ring Opening Polymerization (ROP) for the syntheses of block copolymers.

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Yagci et al. reported a one-pot synthetic approach to BCPs using the combination of ATRP and ROP methods simultaneously.
“Yagci et al. reported a one-pot synthetic approach to BCPs using the combination of ATRP and ring opening polymerization (ROP) methods simultaneously [56].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [56]

Emerging applications of stimuli-responsive polymer materials
Stuart, M. A. C., Huck, W. T. S., Genzer, J., Müller, M., Ober, C. K., Stamm, M., Sukhorukov, G. B., Szleifer, I. G., Tsukruk, V. V., Urban, M. W., et al. (2010) · Nature Materials · doi:10.1038/nmat2614 · Cited by 5,786
Controlled/living radical polymerization: atom transfer radical polymerization in the presence of transition-metal complexes
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Block copolymer micelles for drug delivery: design, characterization and biological significance
Kataoka, K., Harada, A., & Nagasaki, Y. (2001) · Advanced Drug Delivery Reviews · doi:10.1016/s0169-409x(00)00124-1 · Cited by 3,506
Biodegradable block copolymers as injectable drug-delivery systems
Jeong, B., Bae, Y. H., Lee, D. S., & Kim, S. W. (1997) · Nature · doi:10.1038/42218 · Cited by 2,011
Unconventional Methods for Fabricating and Patterning Nanostructures
Younan Xia, A., Rogers, J. A., Paul, K. E., & Whitesides, G. M. (1999) · Chemical Reviews · doi:10.1021/cr980002q · Cited by 1,548
Synthetic applications of eosin Y in photoredox catalysis
Hari, D. P., & König, B. (2014) · Chemical Communications · doi:10.1039/c4cc00751d · Cited by 1,080
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., de Alaniz, J. R., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 948
Green chemistry: challenges and opportunities
Clark, J. H. (1999) · Green Chemistry · doi:10.1039/a807961g · Cited by 896
Organocatalyzed atom transfer radical polymerization driven by visible light
Theriot, J. C., Lim, C., Yang, H., Ryan, M. D., Musgrave, C. B., & Miyake, G. M. (2016) · Science · doi:10.1126/science.aaf3935 · Cited by 813
Nanostructure fabrication using block copolymers
Hamley, I. W. (2003) · Nanotechnology · doi:10.1088/0957-4484/14/10/201 · Cited by 773
Ionic Self‐Assembly: Facile Synthesis of Supramolecular Materials
Faul, C. F. J., & Antonietti, M. (2003) · Advanced Materials · doi:10.1002/adma.200300379 · Cited by 761
Functional Block Copolymers: Nanostructured Materials with Emerging Applications
Schacher, F. H., Rupar, P. A., & Manners, I. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200310 · Cited by 705
Block Copolymers: Past Successes and Future Challenges
Lodge, T. P. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200290073 · Cited by 568
Organic Catalysis for Ring-Opening Polymerization
Dove, A. P. (2012) · ACS Macro Letters · doi:10.1021/mz3005956 · Cited by 559
Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization
Jakubowski, W., & Matyjaszewski, K. A. (2005) · Macromolecules · doi:10.1021/ma047389l · Cited by 552
Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies
Pan, X., Fang, C., Fantin, M., Malhotra, N., So, W. Y., Peteanu, L. A., Isse, A. A., Gennaro, A., Liu, P., & Matyjaszewski, K. A. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13455 · Cited by 470
Light‐Induced Click Reactions
Taşdelen, M. A., & Yağcı, Y. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201208741 · Cited by 463
Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
Miyake, G. M., & Theriot, J. C. (2014) · Macromolecules · doi:10.1021/ma502044f · Cited by 359
Mechanistic transformations involving living and controlled/living polymerization methods
Yağcı, Y., & Taşdelen, M. A. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.07.003 · Cited by 348
Light‐Regulated Polymerization under Near‐Infrared/Far‐Red Irradiation Catalyzed by Bacteriochlorophyll a
Shanmugam, S., Xu, J., & Boyer, C. A. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201510037 · Cited by 342
Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile
Pan, X., Lamson, M., Yan, J., & Matyjaszewski, K. A. (2015) · ACS Macro Letters · doi:10.1021/mz500834g · Cited by 321
Chemical Aspects of Three-Dimensional Photonic Crystals
Moon, J. H., & Yang, S. M. (2009) · Chemical Reviews · doi:10.1021/cr900080v · Cited by 267
Metal-free photoinduced electron transfer–atom transfer radical polymerization (PET–ATRP) via a visible light organic photocatalyst
Liu, X., Zhang, L., Cheng, Z., & Zhu, X. (2015) · Polymer Chemistry · doi:10.1039/c5py01765c · Cited by 256
Photoinduced Atom Transfer Radical Polymerization with ppm-Level Cu Catalyst by Visible Light in Aqueous Media
Pan, X., Malhotra, N., Simakova, A., Wang, Z., Konkolewicz, D., & Matyjaszewski, K. A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11599 · Cited by 247
One-Pot Synthesis of ABC Type Triblock Copolymers via in situ Click [3 + 2] and Diels−Alder [4 + 2] Reactions
Durmaz, H., Dağ, A., Altintas, O., Erdogan, T., Hızal, G., & Tunca, Ü. (2006) · Macromolecules · doi:10.1021/ma061819l · Cited by 238
Photoacid-mediated ring opening polymerization driven by visible light
Fu, C., Xu, J., & Boyer, C. A. (2016) · Chemical Communications · doi:10.1039/c6cc03084j · Cited by 223
Interfacial behavior of block polyelectrolytes. 1. Evidence for novel surface micelle formation
Zhu, J., Eisenberg, A., & Lennox, R. B. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00015a011 · Cited by 190
Stereo-, Temporal and Chemical Control through Photoactivation of Living Radical Polymerization: Synthesis of Block and Gradient Copolymers
Shanmugam, S., & Boyer, C. A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05903 · Cited by 167
Photoinduced Free Radical Promoted Copper(I)-Catalyzed Click Chemistry for Macromolecular Syntheses
Taşdelen, M. A., Yılmaz, G., Işkın, B., & Yağcı, Y. (2011) · Macromolecules · doi:10.1021/ma202438w · Cited by 166
Polyaromatic Structures as Organo-Photoinitiator Catalysts for Efficient Visible Light Induced Dual Radical/Cationic Photopolymerization and Interpenetrated Polymer Networks Synthesis
Tehfe, M., Lalevée, J., Telitel, S., Contal, E., Dumur, F., Gigmès, D., Bertin, D., Nechab, M., Graff, B., Morlet‐Savary, F., et al. (2012) · Macromolecules · doi:10.1021/ma300760c · Cited by 151
LED and visible light-induced metal free ATRP using reducible dyes in the presence of amines
Kütahya, C., Aykac, F. S., Yılmaz, G., & Yağcı, Y. (2016) · Polymer Chemistry · doi:10.1039/c6py01417h · Cited by 150
Photoinitiated Metal-Free Controlled/Living Radical Polymerization Using Polynuclear Aromatic Hydrocarbons
Allushi, A., Steffen Jockusch, B., Yılmaz, G., & Yağcı, Y. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b01752 · Cited by 136
Self-citation
Photocatalyzed Cu-Based ATRP Involving an Oxidative Quenching Mechanism under Visible Light
Yang, Q., Dumur, F., Morlet‐Savary, F., Poly, J., & Lalevée, J. (2015) · Macromolecules · doi:10.1021/ma502384y · Cited by 114
Living Cationic Polymerization of Vinyl Ethers through a Photoinduced Radical Oxidation/Addition/Deactivation Sequence
Çiftçi, M., Yoshikawa, Y., & Yağcı, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201609357 · Cited by 113
A Remarkable Visible Light Effect on Atom-Transfer Radical Polymerization
Guan, Z., & Smart, B. E. (2000) · Macromolecules · doi:10.1021/ma000646b · Cited by 109
Photovoltaic enhancement of organic solar cells by a bridged donor-acceptor block copolymer approach
Sun, S., Zhang, C. H., Ledbetter, A. J., Choi, S., Seo, K., Bonner, C. E., Drees, M., & Sariçiftçi, N. S. (2007) · Applied Physics Letters · doi:10.1063/1.2437100 · Cited by 106
ATRP of MMA with ppm Levels of Iron Catalyst
Wang, Y., Zhang, Y., Parker, B. F., & Matyjaszewski, K. A. (2011) · Macromolecules · doi:10.1021/ma200771r · Cited by 101
Aqueous Copper(II) Photoinduced Polymerization of Acrylates: Low Copper Concentration and the Importance of Sodium Halide Salts
Jones, G. R., Whitfield, R., Anastasaki, A., & Haddleton, D. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02701 · Cited by 99
A “Catalyst Switch” Strategy for the Sequential Metal-Free Polymerization of Epoxides and Cyclic Esters/Carbonate
Zhao, J., Pahovnik, D., Gnanou, Y., & Hadjichristidis, N. (2014) · Macromolecules · doi:10.1021/ma500830v · Cited by 92
Sequential polymerization of ethylene oxide, ε-caprolactone and l -lactide: a one-pot metal-free route to tri- and pentablock terpolymers
Zhao, J., Pahovnik, D., Gnanou, Y., & Hadjichristidis, N. (2014) · Polym. Chem. · doi:10.1039/c4py00429a · Cited by 79
Photo-induced living radical polymerization of acrylates utilizing a discrete copper( ii )–formate complex
Anastasaki, A., Nikolaou, V., Brandford-Adams, F., Nurumbetov, G., Zhang, Q., Clarkson, G. J., Fox, D. J., Wilson, P., Kempe, K., & Haddleton, D. M. (2015) · Chemical Communications · doi:10.1039/c4cc09916h · Cited by 76
The active role of excited states of phenothiazines in photoinduced metal free atom transfer radical polymerization: singlet or triplet excited states?
Steffen Jockusch, B., & Yağcı, Y. (2016) · Polymer Chemistry · doi:10.1039/c6py01410k · Cited by 76
Spatially Selective Functionalization of Conducting Polymers by “Electroclick” Chemistry
Hansen, T., Daugaard, A. E., Hvilsted, S., & Larsen, N. B. (2009) · Advanced Materials · doi:10.1002/adma.200900980 · Cited by 70
Copper( ii ) gluconate (a non-toxic food supplement/dietary aid) as a precursor catalyst for effective photo-induced living radical polymerisation of acrylates
Nikolaou, V., Anastasaki, A., Alsubaie, F. M., Simula, A., Fox, D. J., & Haddleton, D. M. (2015) · Polymer Chemistry · doi:10.1039/c5py00406c · Cited by 59
Photoinduced Copper(I)‐Catalyzed Click Chemistry by the Electron Transfer Process Using Polynuclear Aromatic Compounds
Yılmaz, G., Işkın, B., & Yağcı, Y. (2014) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201400010 · Cited by 53
One‐step synthesis of block copolymers using a hydroxyl‐functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H. (2012) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26464 · Cited by 51
Block and graft polymers their synthesis, especially by living polymer technique, and their properties
Szwarc, M. (1973) · Polymer Engineering and Science · doi:10.1002/pen.760130102 · Cited by 30
Electron Holography on Beam Sensitive Materials: Organic Polymers and Mesoporous Silica
Simon, P., Huhle, R., Lehmann, M., Lichte, H., Mönter, D., Bieber, T., Reschetilowski, W., Adhikari, R., & Michler, G. H. (2002) · Chemistry of Materials · doi:10.1021/cm011140q · Cited by 25
Simultaneous dual living polymerizations: a novel one-step approach to block and graft copolymers
(1998) · doi:10.1002/(sici)1521-3773(19980518)37:9
Untitled work
Kolb (2001) · doi:10.1002/1521-3773(20010601)40:11

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Self-citation

Authors: Aydogan, C., Kutahya, C., Allushi, A., Yilmaz, G., & Yagci, Y.
Affiliations: Department of Chemistry
Istanbul Technical University (TR)
ORCID: Allushi, Andrit
Yagci, Yusuf
Venue: Polymer Chemistry
Publisher: Royal Society of Chemistry (RSC)
Published: 2017
Volume: 8
Issue: 19
Pages: 2899-2903
ISSN: 1759-9954 (ISSN-L)
1759-9962
DOI: 10.1039/c7py00069c
OpenAlex: W2605707874
Cited by: 78
References: 50
Citations by year: 2026: 2 · 2025: 8 · 2024: 3 · 2023: 6 · 2022: 4 · 2021: 10 · 2020: 12 · 2019: 3 · 2018: 21 · 2017: 9
FWCI: 5.15
Type: journal article
Language: en
Open access: closed
Locations: Polymer Chemistry (publishedVersion)
Istanbul Technical University Academic Open Archive (Istanbul Technical University) (submittedVersion)
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
Keywords: block copolymer synthesis, atom transfer radical polymerization, ring-opening polymerization, metal-free polymerization, solar photocatalysis, photopolymerization

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Block copolymer synthesis in one shot: concurrent metal-free ATRP and ROP processes under sunlight

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