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Stimuli-Responsive Bicomponent Polymer Janus Particles by “Grafting from”/“Grafting to” Approaches
Abstract
We report preparation of stimuli-responsive bicomponent polymeric Janus particles and investigation of their switching behavior. The first polymer was immobilized on one side of silica particles using the surface-initiated atom transfer radical polymerization, “grafting from” approach. The second polymer was immobilized using the “grafting to” method by reaction between reactive terminating groups of polymer chains and functional groups on the particle surface. On the example of mixed oppositely charged polyelectrolyte Janus particles decorated with poly(acrylic acid) and poly(2-vinylpyridine) chains, we demonstrate stimuli-responsive aggregation/disaggregation behavior upon pH changes.
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Citations
Cited by
Janus Particles: Synthesis, Self-Assembly, Physical Properties, and Applications
Walther, A., & Müller, A. H. E. (2013) · Chemical Reviews · doi:10.1021/cr300089t · Cited by 1,769
Kocak, G., Tuncer, C., & Bütün, V. (2017) · Polymer Chemistry · doi:10.1039/c6py01872f · Cited by 1,189
Motornov, M., Roiter, Y., Tokarev, I., & Minko, S. (2010) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.10.004 · Cited by 773
Hui, C. M., Pietrasik, J., Schmitt, M., Mahoney, C., Choi, J., Bockstaller, M. R., & Matyjaszewski, K. (2014) · Chemistry of Materials · doi:10.1021/cm4023634 · Cited by 367
Chen, J.-K., & Chang, C.-J. (2014) · Materials · doi:10.3390/ma7020805 · Cited by 193
Metadata
- Authors
- Berger, S., Synytska, A., Ionov, L., Eichhorn, K.-J., & Stamm, M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-21
- Volume
- 41
- Issue
- 24
- Pages
- 9669-9676
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2010788219
- Cited by
- 204
- References
- 0
- FWCI
- 7.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Stimuli-Responsive Bicomponent Polymer Janus Particles by “Grafting from”/“Grafting to” Approaches. https://app.cochat.ai/papers/10.1021/ma802089h
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- Berger, S., Synytska, A., Ionov, L., Eichhorn, K.-J., & Stamm, M. (2008). Stimuli-Responsive Bicomponent Polymer Janus Particles by “Grafting from”/“Grafting to” Approaches. Macromolecules. https://doi.org/10.1021/ma802089h
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