The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Surface-Dependent Kinetics of Cu(0)-Wire-Catalyzed Single-Electron Transfer Living Radical Polymerization of Methyl Acrylate in DMSO at 25 °C
Abstract
The effect of Cu(0) wire dimensions on the Cu(0) wire/Me 6 -TREN-catalyzed heterogeneous single-electron transfer living radical polymerization (SET-LRP) of methyl acrylate (MA) initiated with methyl 2-bromopropionate (MBP) in DMSO at 25 °C was analyzed by kinetic experiments. These kinetic results were compared with those of Cu(0) powder/Me 6 -TREN-catalyzed SET-LRP. Both wire and powder produce perfect SET-LRP with a first-order rate of polymerization in growing species up to 100% conversion. Nevertheless, Cu(0) wire experiments demonstrated SET-LRP with greater perfection, allowing for the accurate determination of the external rate order (vis-à-vis surface area) for heterogeneous Cu(0) catalyst and accurate prediction of k p app from wire dimension. Cu(0) wire also exhibited a significantly greater control of molecular weight distribution than Cu(0) powder. The combined advantages of easier catalyst preparation, handling, predictability, tunability, simple recovery/recycling, and enhanced control of molecular weight distribution make Cu(0)-wire-catalyzed SET-LRP the ideal methodology for the synthesis of tailored polyacrylates.
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Use of ascorbic acid as reducing agent for synthesis of well-defined polymers by arget atrp
Min, K., Gao, H., & Matyjaszewski, K. (2007) · Macromolecules · doi:10.1021/ma0702041 · Cited by 380
Cited by
Mechanically-Induced Chemical Changes in Polymeric Materials
Caruso, M. M., Davis, D. A., Shen, Q., Odom, S. A., Sottos, N. R., White, S. R., & Moore, J. S. (2009) · Chemical Reviews · doi:10.1021/cr9001353 · Cited by 1,372
Zoppe, J. O., Ataman, N. C., Mocny, P., Wang, J., Moraes, J., & Klok, H.-A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00314 · Cited by 1,046
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
SARA ATRP or SET-LRP. End of controversy?
Konkolewicz, D., Wang, Y., Krys, P., Zhong, M., Isse, A. A., Gennaro, A., & Matyjaszewski, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00149d · Cited by 314
Double-bond-containing polyallene-based triblock copolymers via phenoxyallene and (meth)acrylate
Ding, A., Lu, G., Guo, H., & Huang, X. (2017) · Scientific Reports · doi:10.1038/srep43706 · Cited by 8
Metadata
- Authors
- Nguyen, N. H., Rosen, B. M., Lligadas, G., & Percec, V.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-17
- Volume
- 42
- Issue
- 7
- Pages
- 2379-2386
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2085056001
- Cited by
- 249
- References
- 3
- FWCI
- 18.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nguyen, N. H., Rosen, B. M., Lligadas, G., & Percec, V. (2009). Surface-Dependent Kinetics of Cu(0)-Wire-Catalyzed Single-Electron Transfer Living Radical Polymerization of Methyl Acrylate in DMSO at 25 °C. Macromolecules. https://doi.org/10.1021/ma8028562
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