Double-bond-containing polyallene-based triblock copolymers via phenoxyallene and (meth)acrylate
Open accessAbstract
A series of ABA triblock copolymers, consisting of double-bond-containing poly(phenoxyallene) (PPOA), poly(methyl methacrylate) (PMMA), or poly(butyl acrylate) (PBA) segments, were synthesized by sequential free radical polymerization and atom transfer radical polymerization (ATRP). A new bifunctional initiator bearing azo and halogen-containing ATRP initiating groups was first prepared followed by initiating conventional free radical homopolymerization of phenoxyallene with cumulated double bond to give a PPOA-based macroinitiator with ATRP initiating groups at both ends. Next, PMMA-b-PPOA-b-PMMA and PBA-b-PPOA-b-PBA triblock copolymers were synthesized by ATRP of methyl methacrylate and n-butyl acrylate initiated by the PPOA-based macroinitiator through the site transformation strategy. These double-bond-containing triblock copolymers are stable under UV irradiation and free radical circumstances.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Huang and coworkers synthesized a series of ABA triblock copolymers consisting of PPOA, PMMA, or PBA segments using sequential free radical polymerization and ATRP.
“Huang and coworkers synthesized a series of ABA triblock copolymers, consisting of double-bond-containing poly(phenoxyallene) (PPOA), PMMA, or PBA segments using sequential free radical polymerization and ATRP [30].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [30]
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
Atom Transfer Radical Polymerization
Matyjaszewski, K. A., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,646 · see citing works
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622 · see citing works
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046 · see citing works
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397 · see citing works
Percec, V., Guliashvili, T., Ladislaw, J. S., Finne‐Wistrand, A., Stjerndahl, A., Sienkowska, M. J., Monteiro, M. J., & Sahoo, S. K. (2006) · Journal of the American Chemical Society · doi:10.1021/ja065484z · Cited by 1,139 · see citing works
"Living" Radical Polymerization of Styrene Initiated by Arenesulfonyl Chlorides and CuI(bpy)nCl
Percec, V., & Barboiu, B. (1995) · Macromolecules · doi:10.1021/ma00127a057 · Cited by 833 · see citing works
Toward Living Radical Polymerization
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Accounts of Chemical Research · doi:10.1021/ar800075n · Cited by 735 · see citing works
Mechanistic transformations involving living and controlled/living polymerization methods
Yağcı, Y., & Taşdelen, M. A. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.07.003 · Cited by 339 · see citing works
Self-Assembled Polystyrene-block-poly(ethylene oxide) Micelle Morphologies in Solution
Bhargava, P., Zheng, J. X., Li, P., Quirk, R. P., Harris, F. W., & Cheng, S. Z. D. (2006) · Macromolecules · doi:10.1021/ma060677s · Cited by 254 · see citing works
Nguyen, N. H., Rosen, B. M., Lligadas, G., & Percec, V. (2009) · Macromolecules · doi:10.1021/ma8028562 · Cited by 250 · see citing works
Mueller, L., Jakubowski, W., Tang, W., & Matyjaszewski, K. A. (2007) · Macromolecules · doi:10.1021/ma071130w · Cited by 161 · see citing works
Functionalization of Polymers by Metal-Mediated Processes
McGrath, M. P., Sall, E. D., & Tremont, S. J. (1995) · Chemical Reviews · doi:10.1021/cr00034a004 · Cited by 160 · see citing works
Anastasaki, A., Waldron, C., Wilson, P., Boyer, C. A., Zetterlund, P. B., Whittaker, M. R., & Haddleton, D. M. (2013) · ACS Macro Letters · doi:10.1021/mz4004198 · Cited by 129 · see citing works
Williams, V. A., Ribelli, T. G., Chmielarz, P., Park, S., & Matyjaszewski, K. A. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512519j · Cited by 108 · see citing works
Walther, A., Goldmann, A. S., Yelamanchili, R. S., et al. (2008) · Macromolecules · doi:10.1021/ma7026148 · Cited by 96 · see citing works
Functionally terminated poly(methyl acrylate) by SET‐LRP initiated with CHBr3 and CHI3
Lligadas, G., Ladislaw, J. S., Guliashvili, T., et al. (2007) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22379 · Cited by 88 · see citing works
A Novel Living Coordination Polymerization of Phenylallene Derivatives by π-Allylnickel Catalyst
Takagi, K., Tomita, I., & Endo, T. (1997) · Macromolecules · doi:10.1021/ma9708959 · Cited by 85 · see citing works
A Novel Living Coordination Polymerization of Methoxyallene by .pi.-Allylnickel Catalyst
Tomita, I., Kondo, Y., Takagi, K., et al. (1994) · Macromolecules · doi:10.1021/ma00093a052 · Cited by 83 · see citing works
Pentablock star shaped polymers in less than 90 minutes via aqueous SET-LRP
Aksakal, R., Resmini, M., & Becer, C. R. (2015) · Polymer Chemistry · doi:10.1039/c5py01623a · Cited by 70 · see citing works
Uchiike, C., Terashima, T., Ouchi, M., et al. (2007) · Macromolecules · doi:10.1021/ma071639r · Cited by 68 · see citing works
Synthesis and Aggregation of Double Hydrophilic Diblock Glycopolymers via Aqueous SET-LRP
Zhang, Q., Wilson, P., Anastasaki, A., McHale, R., & Haddleton, D. M. (2014) · ACS Macro Letters · doi:10.1021/mz5001724 · Cited by 66 · see citing works
Villarroya, S., Zhou, J., Duxbury, C. J., et al. (2005) · Macromolecules · doi:10.1021/ma052142p · Cited by 64 · see citing works
Interaction of epoxy and vinyl ethers during photoinitiated cationic polymerization
Rajaraman, S. K., Mowers, W. A., & Crivello, J. V. (1999) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/(sici)1099-0518(19991101)37:21 · Cited by 64 · see citing works
Simula, A., Nikolaou, V., Anastasaki, A., Alsubaie, F. M., Nurumbetov, G., Wilson, P., Kempe, K., & Haddleton, D. M. (2015) · Polymer Chemistry · doi:10.1039/c4py01802h · Cited by 59 · see citing works
Dynamics of Hole Trapping by G, GG, and GGG in DNA
Davis, W. B., Naydenova, I., Haselsberger, R., Ogrodnik, A., Giese, B., & Michel‐Beyerle, M. E. (2000) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20001016)39:20 · Cited by 58 · see citing works
Yu, Z., Ma, C., Wang, Q., et al. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02759 · Cited by 58 · see citing works
Novel linear-dendritic-like amphiphilic copolymers: synthesis and self-assembly characteristics
Fan, X., Wang, Z., Yuan, D., Sun, Y., Li, Z., & He, C. (2014) · Polymer Chemistry · doi:10.1039/c4py00065j · Cited by 53 · see citing works
pH-Responsive Diblock Copolymers Prepared by the Dual Initiator Strategy
Bernaerts, K. V., Willet, N., Camp, W. V., et al. (2006) · Macromolecules · doi:10.1021/ma052625t · Cited by 51 · see citing works
Endo, T., Takagi, K., & Tomita, I. (1997) · Tetrahedron · doi:10.1016/s0040-4020(97)00956-3 · Cited by 45 · see citing works
Novel polymerization methods for allene derivatives
Endo, T. (1997) · Progress in Polymer Science · doi:10.1016/s0079-6700(96)00022-6 · Cited by 43 · see citing works
Mochizuki, K., & Tomita, I. (2006) · Macromolecules · doi:10.1021/ma052374o · Cited by 43 · see citing works
Living Coordination Polymerization of N-Allenylamides by π-Allylnickel Catalysts
Takagi, K., Tomita, I., & Endo, T. (1998) · Macromolecules · doi:10.1021/ma9800921 · Cited by 41 · see citing works
Hu, Y.-Y., Su, M., Ma, C., et al. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01120 · Cited by 36 · see citing works
Le, D. P., Phan, T. N. T., Autissier, L., et al. (2016) · Polymer Chemistry · doi:10.1039/c5py01934f · Cited by 31 · see citing works
Wang, F., Dong, B., Liu, H., et al. (2014) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201400465 · Cited by 28 · see citing works
Triftaridou, A. I., Loizou, E., & Patrickios, C. S. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22773 · Cited by 25 · see citing works
Takagi, K., Endo, T., Tomita, I., et al. (1998) · Chemical Communications · doi:10.1039/a708786a · Cited by 22 · see citing works
Li, H., Rathi, S. R., Sterner, E. S., et al. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26840 · Cited by 21 · see citing works
Elladiou, M., & Patrickios, C. S. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b01823 · Cited by 20 · see citing works
Yokozawa, T., Ito, N., & Endo, T. (1988) · Chemistry Letters · doi:10.1246/cl.1988.1955 · Cited by 18 · see citing works
Jiang, B., Nykypanchuk, D., Endoh, M. K., et al. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02515 · Cited by 16 · see citing works
Zhu, P. C., Wu, Z., & Pittman, C. U. (1997) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/(sici)1099-0518(199702)35:3 · Cited by 15 · see citing works
Polyallene-based graft copolymer via 6-methyl-1,2-heptadien-4-ol and methyl methacrylate
Zhang, X., Shen, Z., Li, L., et al. (2007) · Polymer · doi:10.1016/j.polymer.2007.07.037 · Cited by 15 · see citing works
Hashimoto, T., Imaeda, T., Irie, S., et al. (2015) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27542 · Cited by 15 · see citing works
Novel graft copolymer containing a polyallene backbone and poly(tert‐butyl acrylate) side chains
Zhang, X., Peng, D., Lu, G., et al. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21796 · Cited by 13 · see citing works
Self-citationBanerjee, S., Maji, T., Paira, T. K., et al. (2014) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201300741 · Cited by 11 · see citing works
Synthesis of polyallene‐based graft copolymer via 6‐methyl‐1,2‐heptadien‐4‐ol and styrene
Zhang, X., Shen, Z., Li, L., et al. (2007) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22296 · Cited by 11 · see citing works
Du, V. A., Qiu, H., Winnik, M. A., Whittell, G. R., & Ian Manners, A. (2016) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201600028 · Cited by 11 · see citing works
Kino, T., & Tomita, I. (2005) · Polymer Bulletin · doi:10.1007/s00289-005-0435-9 · Cited by 10 · see citing works
Shin, S., Moon, S., Seo, M., & Kim, S. Y. (2016) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.28182 · Cited by 8 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Block Copolymers: Synthesis, Self-Assembly, and Applications
Feng, H., Lu, X., Wang, W., Kang, N.-G., & Mays, J. (2017) · Polymers · doi:10.3390/polym9100494 · Cited by 467 · see citing works
- Authors
- Ding, A., Lu, G., Guo, H., & Huang, X.
- Affiliations
- Chinese Academy of Sciences (CN)
- Fudan University (CN)
- Corresponding author
- Guo, Hao
- Huang, Xiaoyu
- Venue
- Scientific Reports
- Published
- 2017-03-02
- Volume
- 7
- Issue
- 1
- Pages
- 43706-43706
- ISSN
- 2045-2322 (ISSN-L)
- PMC
- PMC5333076
- OpenAlex
- W2594475701
- Cited by
- 8
- References
- 51
- Citations by year
- 2024: 1 · 2023: 1 · 2021: 1 · 2020: 2 · 2017: 3
- FWCI
- 0.57
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Scientific Reports (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (XDB20000000, 21274023)
- Chinese Academy of Sciences (XDB20000000)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
- Keywords
- ABA triblock copolymers, poly(methyl methacrylate), poly(butyl acrylate), atom transfer radical polymerization, radical polymerization, macroinitiator, bifunctional initiator, azo initiators, site transformation, UV stability, radical stability
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review