The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Clicking Pentafluorostyrene Copolymers: Synthesis, Nanoprecipitation, and Glycosylation
Abstract
Glycopolymers consisting of styrene (St) and pentafluorostyrene (PFS) were synthesized by a combination of nitroxide-mediated polymerization and “click” chemistry. A series of well-defined homopolymers as well as block and random copolymers of St and PFS were obtained with different ratios by using Bloc Builder as an alkoxyamine initiator. Some copolymers showed self-assembly behavior into regular nanospheres with diameters ranging from 70 to 720 nm by applying the nanoprecipitation technique. In addition, a thiol−glycoside (2,3,4,6-tetra- O -acetyl-1-thio-β- d -glucopyranose) was reacted under ambient conditions with PFS moieties on the polymeric backbone utilizing a thiol− para fluoro “click” reaction. This nucleophilic substitution reaction was performed with high yields, and the reaction kinetic was monitored online with 19 F NMR spectroscopy. Finally, the deacetylation of the protected glucose moieties was carried out to yield well-defined glycopolymers. The polymers were characterized in detail by 1 H, 13 C, and 19 F NMR spectroscopy, size exclusion chromatography, and MALDI TOF-MS.
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Cites
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Biodegradable polymeric nanoparticles as drug delivery devices
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The convergence of synthetic organic and polymer chemistries
Hawker, C. J., & Wooley, K. L. (2005) · Science · doi:10.1126/science.1109778 · Cited by 1,298
Cited by
Isikgor, F. H., & Becer, C. R. (2015) · Polymer Chemistry · doi:10.1039/c5py00263j · Cited by 2,775
Self-citationThiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
Lowe, A. B. (2010) · Polym. Chem. · doi:10.1039/b9py00216b · Cited by 1,563
Nitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Click chemistry strategies for the accelerated synthesis of functional macromolecules
Geng, Z., Shin, J. J., Xi, Y., & Hawker, C. J. (2021) · Journal of Polymer Science · doi:10.1002/pol.20210126 · Cited by 269
Metadata
- Authors
- Becer, C. R., Babiuch, K., Pilz, D., Hornig, S., Heinze, T., Gottschaldt, M., & Schubert, U. S.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-03-12
- Volume
- 42
- Issue
- 7
- Pages
- 2387-2394
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2124502694
- Cited by
- 238
- References
- 4
- FWCI
- 12.45
- Type
- journal article
- Language
- en
- Open access
- closed
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