The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Transcrystallization in Mcl-PHAs/Cellulose Whiskers Composites
Abstract
Nanocomposite materials were prepared from an elastomeric medium-chain-length poly(hydroxyalkanoate) (Mcl-PHA) latex as semicrystalline matrix using a colloidal suspension of hydrolyzed cellulose whiskers as natural and biodegradable filler. After stirring, the preparations were cast and evaporated. High-performance materials were obtained from this system, preserving the natural character of PHA. However, differences were reported by comparison with amorphous PHA filled systems. These differences were ascribed to a transcrystallization phenomenon of semicrystalline PHA on cellulose whiskers, evidenced by dynamic mechanical analysis. Transcrystallization hindered the mechanical percolation of cellulose whiskers and the formation of a rigid network within the polymer matrix during the film formation by evaporation. The whiskers network can reorganize under thermal aging.
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Cited by
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Self-citationCellulosic Bionanocomposites: A Review of Preparation, Properties and Applications
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BackgroundSelf-citationProduction of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications
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Metadata
- Authors
- Dufresne, A., Kellerhals, M. B., & Witholt, B.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-10-09
- Volume
- 32
- Issue
- 22
- Pages
- 7396-7401
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2004525074
- Cited by
- 236
- References
- 6
- FWCI
- 4.06
- Type
- journal article
- Language
- en
- Open access
- closed
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