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Cited by 187

The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

Competition between Oxidation and Coordination in Cross-Linking of Polystyrene Copolymer Containing Catechol Groups

Xu, Hang, Nishida, Jin, Ma, Wei, Wu, Hui, Kobayashi, Motoyasu, Otsuka, Hideyuki, Takahara, Atsushi·2012·ACS Macro Letters

Abstract

In gelation chemistry, catechol groups are used as cross-linking points. Both oxidation and coordination effects of catechol were investigated for their unique features in chemistry by spectroscopic measurements. Polystyrene copolymers containing catechol groups were synthesized by free radical copolymerization of styrene and N -2-(3′,4′-ditriethylsilyloxyphenyl)ethyl methacrylamide, and the successive deprotection reaction was catalyzed by tetra- n -butylammonium fluoride. The copolymer containing catechol units afforded a dual cross-linking system based on completely different coordination and oxidation chemistries, and the competing cross-linking mechanisms are discussed. These findings are useful and important for paving the way for designing a novel bioinspired artificial adhesive surface coating and curing system.

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Metadata

Authors
Xu, H., Nishida, J., Ma, W., Wu, H., Kobayashi, M., Otsuka, H., & Takahara, A.
Venue
ACS Macro Letters
Published
2012-03-19
Volume
1
Issue
4
Pages
457-460
ISSN
2161-1653 (ISSN-L)
OpenAlex
W2011625425
Cited by
187
References
4
FWCI
6.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Competition between Oxidation and Coordination in Cross-Linking of Polystyrene Copolymer Containing Catechol Groups. https://app.cochat.ai/papers/10.1021/mz200217d
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Xu, H., Nishida, J., Ma, W., Wu, H., Kobayashi, M., Otsuka, H., & Takahara, A. (2012). Competition between Oxidation and Coordination in Cross-Linking of Polystyrene Copolymer Containing Catechol Groups. ACS Macro Letters. https://doi.org/10.1021/mz200217d

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