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Synthesis and Stereocomplex Crystallization of Poly(lactide)–Graphene Oxide Nanocomposites

Sun, Yang, He, Chaobin·2012·ACS Macro Letters

Abstract

Poly(lactide) (PLA)-graphene oxide (GO) nanocomposites were prepared by blending commercial poly(l-lactide) (PLLA) with GO-g-PDLA, where GO-g-PDLA was synthesized via ring-opening polymerization using modified GO as the initiator. Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), and X-ray diffraction (XRD) studies showed that a stereocomplex crystal could be formed between PLLA and GO-g-PDLA. The incorporation of GO nanofillers leads to a lower crystallization activation energy of stereocomplex and a higher crystallinity in solution casting samples, mainly due to the heterogeneous nucleating effect of the well-dispersed covalently bonded GO sheets, while in cold crystallized samples, the crystallinity was low owing to exfoliated GO sheets which may reduce chain mobility and hinder crystal growth.

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Metadata

Authors
Sun, Y., & He, C.
Venue
ACS Macro Letters
Published
2012-05-22
Volume
1
Issue
6
Pages
709-713
ISSN
2161-1653 (ISSN-L)
OpenAlex
W2320066250
Cited by
188
References
2
FWCI
5.77
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synthesis and Stereocomplex Crystallization of Poly(lactide)–Graphene Oxide Nanocomposites. https://app.cochat.ai/papers/10.1021/mz300131u
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Sun, Y., & He, C. (2012). Synthesis and Stereocomplex Crystallization of Poly(lactide)–Graphene Oxide Nanocomposites. ACS Macro Letters. https://doi.org/10.1021/mz300131u

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