The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Preparation of Dynamic Covalent Polymers via Inverse Vulcanization of Elemental Sulfur
Abstract
The synthesis of dynamic covalent polymers with controllable amounts of sulfur–sulfur (S–S) bonds in the polymer backbone via inverse vulcanization of elemental sulfur (S 8 ) and 1,3-diisopropenylbenzene (DIB) is reported. An attractive feature of the inverse vulcanization process is the ability to control the number and dynamic nature of S–S bonds in poly(sulfur- random -(1,3-diisopropenylbenzene)) (poly(S- r -DIB) copolymers by simple variation of S 8 /DIB feed ratios in the copolymerization. S–S bonds in poly(S- r -DIB) copolymers of high sulfur content and sulfur rank were found to be more dynamic upon exposure to either heat, or mechanical stimuli. Interrogation of dynamic S–S bonds was conducted in the solid-state utilizing electron paramagnetic resonance spectroscopy and in situ rheological measurements. Time-dependent rheological property behavior demonstrated a compositional dependence of the healing behavior in the copolymers, with the highest sulfur (80 wt % sulfur) content affording the most rapid dynamic response and recovery of rheological properties.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Inherently Photohealable and Thermal Shape-Memory Polydisulfide Networks
Michal, B. T., Jaye, C. A., Spencer, E. J., & Rowan, S. J. (2013) · ACS Macro Letters · doi:10.1021/mz400318m · Cited by 420
Cited by
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934
Zhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.03.002 · Cited by 586
Sulfur and Its Role In Modern Materials Science
Boyd, D. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604615 · Cited by 512
Malleable and Recyclable Poly(urea‐urethane) Thermosets bearing Hindered Urea Bonds
Zhang, Y., Ying, H., Hart, K. R., Wu, Y., Hsu, A. J., Coppola, A. M., Kim, T. A., Yang, K., Sottos, N. R., White, S. R., et al. (2016) · Advanced Materials · doi:10.1002/adma.201601242 · Cited by 422
Malleable and Recyclable Thermosets: The Next Generation of Plastics
Jin, Y., Lei, Z., Taynton, P., Huang, S., & Zhang, W. (2019) · Matter · doi:10.1016/j.matt.2019.09.004 · Cited by 359
Metadata
- Authors
- Griebel, J. J., Nguyen, N. A., Astashkin, A. V., Glass, R. S., Mackay, M. E., Char, K., & Pyun, J.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-26
- Volume
- 3
- Issue
- 12
- Pages
- 1258-1261
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2312727479
- Cited by
- 175
- References
- 3
- FWCI
- 6.90
- Type
- journal article
- Language
- en
- Open access
- closed
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