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Cited by 349

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Sidewall Amino-Functionalization of Single-Walled Carbon Nanotubes through Fluorination and Subsequent Reactions with Terminal Diamines

Stevens, Joel L., Huang, Aaron Y., Peng, Haiqing, Chiang, Ivana W., Khabashesku, Valery N., Margrave, John L.·2003·Nano Letters

Abstract

Single-walled carbon nanotubes (SWNTs) with the N -alkylidene amino groups covalently attached to their side walls have been prepared starting from colloidal solutions of fluorinated SWNTs (fluoronanotubes) in terminal alkylidene diamines followed by heating at 70−170 °C. On the basis of data from thermal gravimetric and energy-dispersive X-ray analyses, the degree of SWNT functionalization achieved was estimated to be as high as 1 in 8 to 12 sidewall carbons. The demonstrated new C−N functionalization method provides a synthetic tool for binding amino acids, DNA, and polymer matrices to the side walls of the SWNTs as well as yields sidewall amino-functionalized nanotube precursors for the preparation of nylon−SWNT polymer materials.

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Metadata

Authors
Stevens, J. L., Huang, A. Y., Peng, H., Chiang, I. W., Khabashesku, V. N., & Margrave, J. L.
Venue
Nano Letters
Published
2003-01-28
Volume
3
Issue
3
Pages
331-336
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2020125439
Cited by
349
References
1
FWCI
13.78
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Sidewall Amino-Functionalization of Single-Walled Carbon Nanotubes through Fluorination and Subsequent Reactions with Terminal Diamines. https://app.cochat.ai/papers/10.1021/nl025944w
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Stevens, J. L., Huang, A. Y., Peng, H., Chiang, I. W., Khabashesku, V. N., & Margrave, J. L. (2003). Sidewall Amino-Functionalization of Single-Walled Carbon Nanotubes through Fluorination and Subsequent Reactions with Terminal Diamines. Nano Letters. https://doi.org/10.1021/nl025944w

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