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Raman Spectroscopy of Single-Wall Boron Nitride Nanotubes
Open accessAbstract
Single-wall boron nitride nanotubes samples synthesized by laser vaporization of a hexagonal BN target under a nitrogen atmosphere are studied by UV and visible Raman spectroscopy. We show that resonant conditions are necessary for investigating phonon modes of BNNTs. Raman excitation in the UV (229 nm) provides preresonant conditions, allowing the identification of the A1 tangential mode at 1370 cm(-1). This is 5 cm(-1) higher than the E(2g) mode in bulk h-BN. Ab initio calculations show that the lower frequency of bulk h-BN with respect to large diameter nanotubes and the single sheet of h-BN is related to a softening of the sp2 bonds in the bulk due to interlayer interaction.
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Citations
Cited by
Raman spectroscopy as a versatile tool for studying the properties of graphene
Ferrari, A. C., & Basko, D. M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.46 · Cited by 7,405
Self-citationBoron Nitride Nanotubes and Nanosheets
Golberg, D., Bando, Y., Huang, Y., Terao, T., Mitome, M., Tang, C., & Zhi, C. (2010) · ACS Nano · doi:10.1021/nn1006495 · Cited by 2,341
Atomically Thin Boron Nitride: Unique Properties and Applications
Li, L. H., & Chen, Y. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201504606 · Cited by 499
Low-dimensional boron nitride nanomaterials
Pakdel, A., Zhi, C., Bando, Y., & Golberg, D. (2012) · Materials Today · doi:10.1016/s1369-7021(12)70116-5 · Cited by 431
Synthesis of large single-crystal hexagonal boron nitride grains on Cu–Ni alloy
Lu, G., Wu, T., Yuan, Q., Wang, H., Wang, H., Ding, F., Xie, X., & Jiang, M. (2015) · Nature Communications · doi:10.1038/ncomms7160 · Cited by 377
Metadata
- Authors
- Arenal, R., Ferrari, A. C., Reich, S., Wirtz, L., Mevellec, J.-Y., Lefrant, S., Rubio, A., & Loiseau, A.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-07-06
- Volume
- 6
- Issue
- 8
- Pages
- 1812-1816
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2100987623
- Cited by
- 330
- References
- 0
- FWCI
- 6.08
- Type
- journal article
- Language
- en
- Open access
- green
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- Arenal, R., Ferrari, A. C., Reich, S., Wirtz, L., Mevellec, J.-Y., Lefrant, S., Rubio, A., & Loiseau, A. (2006). Raman Spectroscopy of Single-Wall Boron Nitride Nanotubes. Nano Letters. https://doi.org/10.1021/nl0602544
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