Cited by 7,405Graphene research and applications2D Materials and ApplicationsDiamond and Carbon-based Materials Research

Raman spectroscopy as a versatile tool for studying the properties of graphene

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Ferrari, Andrea C., Basko, Denis M.·2013·Nature Nanotechnology

Abstract

Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain, doping, disorder and functional groups. This, in turn, provides insight into all sp(2)-bonded carbon allotropes, because graphene is their fundamental building block. Here we review the state of the art, future directions and open questions in Raman spectroscopy of graphene. We describe essential physical processes whose importance has only recently been recognized, such as the various types of resonance at play, and the role of quantum interference. We update all basic concepts and notations, and propose a terminology that is able to describe any result in literature. We finally highlight the potential of Raman spectroscopy for layered materials other than graphene.

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Crossref · 10.1038/nnano.2013.46

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Authors
Ferrari, A. C., & Basko, D. M.
Affiliations
  • University of Cambridge (GB)
  • Centre National de la Recherche Scientifique (FR)
Corresponding author
Ferrari, Andrea C.
Venue
Nature Nanotechnology
Published
2013-04
Volume
8
Issue
4
Pages
235-246
ISSN
  • 1748-3387 (ISSN-L)
  • 1748-3395
OpenAlex
W2074880343
Cited by
7,405
References
2
Citations by year
2026: 554 · 2025: 547 · 2024: 553 · 2023: 578 · 2022: 598 · 2021: 672 · 2020: 672 · 2019: 705 · 2018: 664 · 2017: 594 · 2016: 528 · 2015: 386 · 2014: 288 · 2013: 64 · 2012: 1
FWCI
190.57
Type
journal article
Language
en
Open access
Locations
  • Nature Nanotechnology (publishedVersion)
  • PubMed (publishedVersion)
  • arXiv (Cornell University) (submittedVersion)
  • HAL (submittedVersion)
  • Cambridge University Engineering Department Publications Database (submittedVersion)
  • Apollo (University of Cambridge) (submittedVersion)
  • arXiv (Cornell University)
  • Apollo
Funders
  • European Commission (314578)
  • Engineering and Physical Sciences Research Council (EP/K017144/1, EP/K01711X/1, EP/G042357/1)
Topics
  • Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
  • Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
  • Physical Sciences › Materials Science › Materials Chemistry › Diamond and Carbon-based Materials Research
Keywords
graphene, Raman spectroscopy, number of layers, layer orientation, edge types, strain, doping, disorder, functional groups, electric and magnetic fields, resonance, quantum interference, terminology, layered materials

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