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Incorporation of Homogeneous, Nanoscale MnO2 within Ultraporous Carbon Structures via Self-Limiting Electroless Deposition: Implications for Electrochemical Capacitors
Abstract
The self-limiting reaction of aqueous permanganate with carbon nanofoams produces conformal, nanoscopic deposits of birnessite ribbons and amorphous MnO2 throughout the ultraporous carbon structure. The MnO2 coating contributes additional capacitance to the carbon nanofoam while maintaining the favorable high-rate electrochemical performance inherent to the ultraporous carbon structure of the nanofoam. Such a three-dimensional design exploits the benefits of a nanoscopic MnO2-carbon interface to produce an exceptionally high area-normalized capacitance (1.5 F cm-2), as well as high volumetric capacitance (90 F cm-3).
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Citations
Cited by
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Jiang, J., Li, Y., Liu, J., Huang, X., Yuan, C., & Lou, X. W. (. (2012) · Advanced Materials · doi:10.1002/adma.201202146 · Cited by 2,473
Liu, J., Jiang, J., Cheng, C., Li, H., Zhang, J., Gong, H., & Fan, H. J. (2011) · Advanced Materials · doi:10.1002/adma.201100058 · Cited by 1,311
Wang, Q., Yan, J., & Fan, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03109e · Cited by 1,225
Nanostructured carbon for energy storage and conversion
Candelaria, S. L., Shao, Y., Zhou, W., Li, X., Xiao, J., Zhang, J.-G., Wang, Y., Liu, J., Li, J., & Cao, G. (2012) · Nano Energy · doi:10.1016/j.nanoen.2011.11.006 · Cited by 975
Metadata
- Authors
- Fischer, A. E., Pettigrew, K. A., Rolison, D. R., Stroud, R. M., & Long, J. W.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-01-13
- Volume
- 7
- Issue
- 2
- Pages
- 281-286
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2031569346
- Cited by
- 590
- References
- 0
- FWCI
- 16.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Incorporation of Homogeneous, Nanoscale MnO2 within Ultraporous Carbon Structures via Self-Limiting Electroless Deposition: Implications for Electrochemical Capacitors. https://app.cochat.ai/papers/10.1021/nl062263i
- The paper
- Fischer, A. E., Pettigrew, K. A., Rolison, D. R., Stroud, R. M., & Long, J. W. (2007). Incorporation of Homogeneous, Nanoscale MnO2 within Ultraporous Carbon Structures via Self-Limiting Electroless Deposition: Implications for Electrochemical Capacitors. Nano Letters. https://doi.org/10.1021/nl062263i
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
