The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Breakdown of the Continuum Stokes−Einstein Relation for Nanoparticle Diffusion
Abstract
Cadmium selenide nanoparticles are found to diffuse approximately 200 times faster in a polymeric liquid than predicted by the Stokes-Einstein relation. This remarkable behavior is hypothesized to be due to the nanoparticles being smaller than the entanglement mesh to create a frictional drag that does not follow continuum expectations, in line with a theoretical calculation presented before. This is one of the first demonstrations of X-ray photo correlation spectroscopy applied to polymeric liquids, which we use to explain the simultaneous 60% viscosity reduction of the mixture through a proposed constraint release mechanism.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Viscoelastic Properties of Polymers
Ferry, J. D., & Myers, H. S. (1961) · Journal of The Electrochemical Society · doi:10.1149/1.2428174 · Cited by 13,487
Viscoelastic Properties of Polymers
Jones, W. M. (1981) · Journal of Non-Newtonian Fluid Mechanics · doi:10.1016/0377-0257(81)80036-5 · Cited by 11,092
The Theory of Polymer Dynamics
Marrucci, G. (1987) · Journal of Non-Newtonian Fluid Mechanics · doi:10.1016/0377-0257(87)85036-x · Cited by 9,749
The theory of polymer dynamics
Doi, M., & Edwards, S. F. (1986) · Cited by 8,928
Quantum Dots for Live Cells, in Vivo Imaging, and Diagnostics
Michalet, X., Pinaud, F. F., Bentolila, L. A., Tsay, J. M., Doose, S., Li, J. J., Sundaresan, G., Wu, A. M., Gambhir, S. S., & Weiss, S. (2005) · Science · doi:10.1126/science.1104274 · Cited by 7,790
A theory of the linear viscoelastic properties of dilute solutions of coiling polymers
Rouse, P. E. (1953) · The Journal of Chemical Physics · doi:10.1063/1.1699180 · Cited by 4,203
The Structure and Rheology of Complex Fluids
Kröger, M., & Vermant, J. (2000) · Applied Rheology · doi:10.1515/arh-2000-0024 · Cited by 3,209
The Structure and Rheology of Complex Fluids
Larson, R. G. (1998) · Cited by 3,188
Russel, W. B., Saville, D. A., & Schowalter, W. R. (1989) · Cambridge University Press eBooks · doi:10.1017/cbo9780511608810 · Cited by 3,033
Molecular volumes and the Stokes-Einstein equation
Edward, J. T. (1970) · Journal of Chemical Education · doi:10.1021/ed047p261 · Cited by 1,819
Cited by
Mobility of Nonsticky Nanoparticles in Polymer Liquids
Cai, L.-H., Panyukov, S., & Rubinstein, M. (2011) · Macromolecules · doi:10.1021/ma201583q · Cited by 379
Bailey, E. J., & Winey, K. I. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101242 · Cited by 371
Hopping Diffusion of Nanoparticles in Polymer Matrices
Cai, L.-H., Panyukov, S., & Rubinstein, M. (2015) · Macromolecules · doi:10.1021/ma501608x · Cited by 278
Ganesan, V., & Jayaraman, A. (2014) · Soft Matter · doi:10.1039/c3sm51864g · Cited by 273
Immobilized Polymer Layers on Spherical Nanoparticles
Harton, S. E., Kumar, S. K., Yang, H., Koga, T., Hicks, K., Lee, H., Mijovic, J., Liu, M., Vallery, R. S., & Gidley, D. W. (2010) · Macromolecules · doi:10.1021/ma902484d · Cited by 270
Metadata
- Authors
- Tuteja, A., Mackay, M. E., Narayanan, S., Asokan, S., & Wong, M. S.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-31
- Volume
- 7
- Issue
- 5
- Pages
- 1276-1281
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2035430859
- Cited by
- 272
- References
- 40
- FWCI
- 6.95
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Breakdown of the Continuum Stokes−Einstein Relation for Nanoparticle Diffusion. https://app.cochat.ai/papers/10.1021/nl070192x
- The paper
- Tuteja, A., Mackay, M. E., Narayanan, S., Asokan, S., & Wong, M. S. (2007). Breakdown of the Continuum Stokes−Einstein Relation for Nanoparticle Diffusion. Nano Letters. https://doi.org/10.1021/nl070192x
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
