The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Breakdown of the Continuum Stokes−Einstein Relation for Nanoparticle Diffusion
Abstract
Cadmium selenide nanoparticles are found to diffuse approximately 200 times faster in a polymeric liquid than predicted by the Stokes-Einstein relation. This remarkable behavior is hypothesized to be due to the nanoparticles being smaller than the entanglement mesh to create a frictional drag that does not follow continuum expectations, in line with a theoretical calculation presented before. This is one of the first demonstrations of X-ray photo correlation spectroscopy applied to polymeric liquids, which we use to explain the simultaneous 60% viscosity reduction of the mixture through a proposed constraint release mechanism.
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Metadata
- Authors
- Tuteja, A., Mackay, M. E., Narayanan, S., Asokan, S., & Wong, M. S.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-31
- Volume
- 7
- Issue
- 5
- Pages
- 1276-1281
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2035430859
- Cited by
- 272
- References
- 40
- FWCI
- 6.95
- Type
- journal article
- Language
- en
- Open access
- closed
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