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Cited by 229

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ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity

Open access
Biener, Monika M., Biener, Juergen, Wichmann, Andre, Wittstock, Arne, Baumann, Theodore F., Bäumer, Marcus, Hamza, Alex V.·2011·Nano Letters

Abstract

Nanoporous metals have many technologically promising applications, but their tendency to coarsen limits their long-term stability and excludes high temperature applications. Here, we demonstrate that atomic layer deposition (ALD) can be used to stabilize and functionalize nanoporous metals. Specifically, we studied the effect of nanometer-thick alumina and titania ALD films on thermal stability, mechanical properties, and catalytic activity of nanoporous gold (np-Au). Our results demonstrate that even only 1 nm thick oxide films can stabilize the nanoscale morphology of np-Au up to 1,000°C, while simultaneously making the material stronger and stiffer. The catalytic activity of np-Au can be drastically increased by TiO(2) ALD coatings. Our results open the door to high-temperature sensor, actuator, and catalysis applications and functionalized electrodes for energy storage and harvesting applications.

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Metadata

Authors
Biener, M. M., Biener, J., Wichmann, A., Wittstock, A., Baumann, T. F., Bäumer, M., & Hamza, A. V.
Venue
Nano Letters
Published
2011-07-11
Volume
11
Issue
8
Pages
3085-3090
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2049478146
Cited by
229
References
2
FWCI
6.51
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity. https://app.cochat.ai/papers/10.1021/nl200993g
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Biener, M. M., Biener, J., Wichmann, A., Wittstock, A., Baumann, T. F., Bäumer, M., & Hamza, A. V. (2011). ALD Functionalized Nanoporous Gold: Thermal Stability, Mechanical Properties, and Catalytic Activity. Nano Letters. https://doi.org/10.1021/nl200993g

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.