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Synthesis and Characterization of Large-Area Graphene and Graphite Films on Commercial Cu–Ni Alloy Foils
Abstract
Controlling the thickness and uniformity during growth of multilayer graphene is an important goal. Here we report the synthesis of large-area monolayer and multilayer, particularly bilayer, graphene films on Cu-Ni alloy foils by chemical vapor deposition with methane and hydrogen gas as precursors. The dependence of the initial stages of graphene growth rate on the substrate grain orientation was observed for the first time by electron backscattered diffraction and scanning electron microscopy. The thickness and quality of the graphene and graphite films obtained on such Cu-Ni alloy foils could be controlled by varying the deposition temperature and cooling rate and were studied by optical microscopy, scanning electron microscopy, atomic force microscopy, and micro-Raman imaging spectroscopy. The optical and electrical properties of the graphene and graphite films were studied as a function of thickness.
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Citations
Cites
Experimental observation of the quantum Hall effect and Berry's phase in graphene
Zhang, Y., Tan, Y.-W., Stormer, H. L., & Kim, P. (2005) · Nature · doi:10.1038/nature04235 · Cited by 13,435
Graphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
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Cited by
Graphene synthesis: relationship to applications
Edwards, R. S., & Coleman, K. S. (2013) · Nanoscale · doi:10.1039/c2nr32629a · Cited by 773
Effects of Polycrystalline Cu Substrate on Graphene Growth by Chemical Vapor Deposition
Wood, J. D., Schmucker, S. W., Lyons, A. S., Pop, E., & Lyding, J. W. (2011) · Nano Letters · doi:10.1021/nl201566c · Cited by 470
Growth of Bilayer Graphene on Insulating Substrates
Yan, Z., Peng, Z., Sun, Z., Yao, J., Zhu, Y., Liu, Z., Ajayan, P. M., & Tour, J. M. (2011) · ACS Nano · doi:10.1021/nn202829y · Cited by 301
Metadata
- Authors
- Chen, S., Cai, W., Piner, R. D., Suk, J. W., Wu, Y., Ren, Y., Kang, J., & Ruoff, R. S.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-08-03
- Volume
- 11
- Issue
- 9
- Pages
- 3519-3525
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2018843275
- Cited by
- 323
- References
- 2
- FWCI
- 15.03
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, S., Cai, W., Piner, R. D., Suk, J. W., Wu, Y., Ren, Y., Kang, J., & Ruoff, R. S. (2011). Synthesis and Characterization of Large-Area Graphene and Graphite Films on Commercial Cu–Ni Alloy Foils. Nano Letters. https://doi.org/10.1021/nl201699j
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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