The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Oscillation of Capacitance inside Nanopores
Abstract
Porous carbons of high surface area are promising as cost-effective electrode materials for supercapacitors. Although great attention has been given to the anomalous increase of the capacitance as the pore size approaches the ionic dimensions, there remains a lack of full comprehension of the size dependence of the capacitance in nanopores. Here we predict from a classical density functional theory that the capacitance of an ionic-liquid electrolyte inside a nanopore oscillates with a decaying envelope as the pore size increases. The oscillatory behavior can be attributed to the interference of the overlapping electric double layers (EDLs); namely, the maxima in capacitance appear when superposition of the two EDLs is most constructive. The theoretical prediction agrees well with the experiment when the pore size is less than twice the ionic diameter. Confirmation of the entire oscillatory spectrum invites future experiments with a precise control of the pore size from micro- to mesoscales.
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Cites
Intermolecular and Surface Forces
(2011) · Intermolecular and Surface Forces · doi:10.1016/b978-0-12-391927-4.10024-6 · Cited by 16,923
Materials for electrochemical capacitors
Simon, P., & Gogotsi, Y. (2008) · Nature Materials · doi:10.1038/nmat2297 · Cited by 16,427
Intermolecular and Surface Forces
(2011) · Elsevier eBooks · doi:10.1016/c2011-0-05119-0 · Cited by 8,968
Electrochemical Capacitors for Energy Management
Miller, J. R., & Simon, P. (2008) · Science · doi:10.1126/science.1158736 · Cited by 4,831
Carbon properties and their role in supercapacitors
Pandolfo, A. G., & Hollenkamp, A. F. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.02.065 · Cited by 4,132
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer
Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., & Taberna, P. L. (2006) · Science · doi:10.1126/science.1132195 · Cited by 4,022
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
Pech, D., Brunet, M., Durou, H., Huang, P., Mochalin, V., Gogotsi, Y., Taberna, P.-L., & Simon, P. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2010.162 · Cited by 2,721
Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor
Largeot, C., Portet, C., Chmiola, J., Taberna, P.-L., Gogotsi, Y., & Simon, P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja7106178 · Cited by 2,445
Wang, D., Li, F., Liu, M., Lu, G. Q., & Cheng, H. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200702721 · Cited by 1,999
Graphene Double-Layer Capacitor with ac Line-Filtering Performance
Miller, J. R., Outlaw, R. A., & Holloway, B. C. (2010) · Science · doi:10.1126/science.1194372 · Cited by 1,373
Cited by
Energy applications of ionic liquids
MacFarlane, D. R., Tachikawa, N., Forsyth, M., Pringle, J. M., Howlett, P. C., Elliott, G. D., Davis, J. H., Watanabe, M., Simon, P., & Angell, C. A. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42099j · Cited by 1,745
New Perspectives on the Charging Mechanisms of Supercapacitors
Forse, A. C., Merlet, C., Griffin, J. M., & Grey, C. P. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02115 · Cited by 729
Carbonaceous Electrode Materials for Supercapacitors
Hao, L., Li, X., & Zhi, L. (2013) · Advanced Materials · doi:10.1002/adma.201301204 · Cited by 710
Revitalizing carbon supercapacitor electrodes with hierarchical porous structures
Liu, T., Zhang, F., Song, Y., & Li, Y. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta05646j · Cited by 621
Rational Design of Nanostructured Electrode Materials toward Multifunctional Supercapacitors
Yan, J., Li, S., Lan, B., Wu, Y., & Lee, P. S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201902564 · Cited by 426
Metadata
- Authors
- Jiang, D.-E., Jin, Z., & Wu, J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-10-28
- Volume
- 11
- Issue
- 12
- Pages
- 5373-5377
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2075051245
- Cited by
- 311
- References
- 34
- FWCI
- 9.34
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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