The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries
Abstract
Tremendous effort has been put into developing viable lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit significant capacity decay over cycling. Herein, we identify a new capacity fading mechanism of the sulfur cathodes, relating to Li(x)S detachment from the carbon surface during the discharge process. This observation is confirmed by ex-situ transmission electron microscopy study and first-principles calculations. We demonstrate that this capacity fading mechanism can be overcome by introducing amphiphilic polymers to modify the carbon surface, rendering strong interactions between the nonpolar carbon and the polar Li(x)S clusters. The modified sulfur cathode show excellent cycling performance with specific capacity close to 1180 mAh/g at C/5 current rate. Capacity retention of 80% is achieved over 300 cycles at C/2.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Wang, Z., Dong, Y., Li, H., Zhao, Z., Bin Wu, H., Hao, C., Liu, S., Qiu, J., & Lou, X. W. (2014) · Nature Communications · doi:10.1038/ncomms6002 · Cited by 1,059
Wood-based nanotechnologies toward sustainability
Jiang, F., Li, T., Li, Y., Zhang, Y., Gong, A., Dai, J., Hitz, E., Luo, W., & Hu, L. (2018) · Advanced Materials · doi:10.1002/adma.201703453 · Cited by 599
Carbon materials for Li–S batteries: Functional evolution and performance improvement
Liang, J., Sun, Z.-H., Li, F., & Cheng, H.-M. (2016) · Energy Storage Materials · doi:10.1016/j.ensm.2015.09.007 · Cited by 593
Nanowires for Electrochemical Energy Storage
Zhou, G., Xu, L., Hu, G., Mai, L., & Cui, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00326 · Cited by 439
Self-citationZhou, W., Xiao, X., Cai, M., & Yang, L. (2014) · Nano Letters · doi:10.1021/nl502238b · Cited by 382
Metadata
- Authors
- Zheng, G., Zhang, Q., Cha, J. J., Yang, Y., Li, W., Seh, Z. W., & Cui, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-02-14
- Volume
- 13
- Issue
- 3
- Pages
- 1265-1270
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2321185616
- Cited by
- 705
- References
- 1
- FWCI
- 50.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zheng, G., Zhang, Q., Cha, J. J., Yang, Y., Li, W., Seh, Z. W., & Cui, Y. (2013). Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries. Nano Letters. https://doi.org/10.1021/nl304795g
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