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Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams
Abstract
Sodium ion (Na(+)) batteries have attracted increased attention for energy storage due to the natural abundance of sodium, but their development is hindered by poor intercalation property of Na(+) in electrodes. This paper reports a detailed study of high capacity, high rate sodium ion energy storage in functionalized high-surface-area nanocellular carbon foams (NCCF). The energy storage mechanism is surface-driven reactions between Na(+) and oxygen-containing functional groups on the surface of NCCF. The surface reaction, rather than a Na(+) bulk intercalation reaction, leads to high rate performance and cycling stability due to the enhanced reaction kinetics and the absence of electrode structure change. The NCCF makes more surface area and surface functional groups available for the Na(+) reaction. It delivers 152 mAh/g capacity at the rate of 0.1 A/g and a capacity retention of 90% for over 1600 cycles.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
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Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
Ding, J., Wang, H., Li, Z., Cui, K., Karpuzov, D., Tan, X., Kohandehghan, A., & Mitlin, D. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02986k · Cited by 818
Zhang, M., Li, Y., Wu, F., Bai, Y., & Wu, C. (2021) · Nano Energy · doi:10.1016/j.nanoen.2020.105738 · Cited by 412
Biomass derived carbon nanoparticle as anodes for high performance sodium and lithium ion batteries
Gaddam, R. R., Yang, D., Narayan, R., Raju, K., Kumar, N. A., & Zhao, X. S. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.05.047 · Cited by 363
Metadata
- Authors
- Shao, Y., Xiao, J., Wang, W., Engelhard, M., Chen, X., Nie, Z., Gu, M., Saraf, L. V., Exarhos, G., Zhang, J.-G., & Liu, J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-24
- Volume
- 13
- Issue
- 8
- Pages
- 3909-3914
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2005571551
- Cited by
- 280
- References
- 1
- FWCI
- 14.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shao, Y., Xiao, J., Wang, W., Engelhard, M., Chen, X., Nie, Z., Gu, M., Saraf, L. V., Exarhos, G., Zhang, J.-G., & Liu, J. (2013). Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Nano Letters. https://doi.org/10.1021/nl401995a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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