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A New Type of Porous Graphite Foams and Their Integrated Composites with Oxide/Polymer Core/Shell Nanowires for Supercapacitors: Structural Design, Fabrication, and Full Supercapacitor Demonstrations

Xia, Xinhui, Chao, Dongliang, Fan, Zhanxi, Guan, Cao, Cao, Xiehong, Zhang, Hua, Fan, Hong Jin·2014·Nano Letters

Abstract

We attempt to meet the general design requirements for high-performance supercapacitor electrodes by combining the strategies of lightweight substrate, porous nanostructure design, and conductivity modification. We fabricate a new type of 3D porous and thin graphite foams (GF) and use as the light and conductive substrates for the growth of metal oxide core/shell nanowire arrays to form integrated electrodes. The nanowire core is Co3O4, and the shell is a composite of conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) and metal oxide (MnO2). To show the advantage of this integrated electrode design (viz., GF + Co3O4/PEDOT-MnO2 core/shell nanowire arrays), three other different less-integrated electrodes are also prepared for comparison. Full supercapacitor devices based on the GF + Co3O4/PEDOT-MnO2 as positive electrodes exhibit the best performance compared to other three counterparts due to an optimal design of structure and a synergistic effect.

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Metadata

Authors
Xia, X., Chao, D., Fan, Z., Guan, C., Cao, X., Zhang, H., & Fan, H. J.
Venue
Nano Letters
Published
2014-02-20
Volume
14
Issue
3
Pages
1651-1658
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2140254781
Cited by
442
References
0
FWCI
27.94
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A New Type of Porous Graphite Foams and Their Integrated Composites with Oxide/Polymer Core/Shell Nanowires for Supercapacitors: Structural Design, Fabrication, and Full Supercapacitor Demonstrations. https://app.cochat.ai/papers/10.1021/nl5001778
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Xia, X., Chao, D., Fan, Z., Guan, C., Cao, X., Zhang, H., & Fan, H. J. (2014). A New Type of Porous Graphite Foams and Their Integrated Composites with Oxide/Polymer Core/Shell Nanowires for Supercapacitors: Structural Design, Fabrication, and Full Supercapacitor Demonstrations. Nano Letters. https://doi.org/10.1021/nl5001778

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