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Cited by 490

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

Song, Jiangxuan, Yu, Zhaoxin, Gordin, Mikhail L., Hu, Shi, Yi, Ran, Tang, Duihai, Walter, Timothy, Regula, Michael, Choi, Daiwon, Li, Xiaolin, Manivannan, Ayyakkannu, Wang, Donghai·2014·Nano Letters

Abstract

Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost and natural abundance of sodium. Here, we report a novel phosphorus/graphene nanosheet hybrid as a high performance anode for sodium-ion batteries through facile ball milling of red phosphorus and graphene stacks. The graphene stacks are mechanically exfoliated to nanosheets that chemically bond with the surfaces of phosphorus particles. This chemical bonding can facilitate robust and intimate contact between phosphorus and graphene nanosheets, and the graphene at the particle surfaces can help maintain electrical contact and stabilize the solid electrolyte interphase upon the large volume change of phosphorus during cycling. As a result, the phosphorus/graphene nanosheet hybrid nanostructured anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially be applied to other phosphorus-based alloy anode materials for sodium-ion batteries.

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Metadata

Authors
Song, J., Yu, Z., Gordin, M. L., Hu, S., Yi, R., Tang, D., Walter, T., Regula, M., Choi, D., Li, X., Manivannan, A., & Wang, D.
Venue
Nano Letters
Published
2014-11-03
Volume
14
Issue
11
Pages
6329-6335
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2104840398
Cited by
490
References
42
FWCI
29.18
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries. https://app.cochat.ai/papers/10.1021/nl502759z
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Song, J., Yu, Z., Gordin, M. L., Hu, S., Yi, R., Tang, D., Walter, T., Regula, M., Choi, D., Li, X., Manivannan, A., & Wang, D. (2014). Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries. Nano Letters. https://doi.org/10.1021/nl502759z

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