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Ionic Selectivity of Single Nanochannels
Abstract
There has been an increasing interest in single nanochannel ionic devices, such as ionic filters that control the type of transported ions and ionic diodes that rectify the ionic flow. In this article, we theoretically investigate the importance of the dimensions, surface charge, electrolyte concentration, and applied bias on nanopore performance. We compare numerical solutions of the Poisson, Nernst-Planck (PNP), and Navier-Stokes (NS) equations with their one-dimensional, analytical approximations. We show that by decreasing the length of the nanopore, the ionic current and ionic selectivity become affected by processes outside the nanochannel. The contribution of electroosmosis is noticeable, especially for highly charged nanochannels, but is insignificant, justifying the use of the simple one-dimensional approximation in many cases. Estimates for the critical electric field at which the nanopore selectivity decreases and the ion current starts to saturate are provided.
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Cited by
Single-layer MoS2 nanopores as nanopower generators
Feng, J., Graf, M., Liu, K., Ovchinnikov, D., Dumcenco, D., Heiranian, M., Nandigana, V., Aluru, N. R., Kis, A., & Radenovic, A. (2016) · Nature · doi:10.1038/nature18593 · Cited by 1,239
Firnkes, M., Pedone, D., Knezevic, J., Döblinger, M., & Rant, U. (2010) · Nano Letters · doi:10.1021/nl100861c · Cited by 473
2D materials as an emerging platform for nanopore-based power generation
Macha, M., Marion, S., Nandigana, V. V. R., & Radenovic, A. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0126-z · Cited by 426
Transport mechanisms in nanopores and nanochannels: can we mimic nature?
Tagliazucchi, M., & Szleifer, I. (2015) · Materials Today · doi:10.1016/j.mattod.2014.10.020 · Cited by 269
How theory and simulation can drive fuel cell electrocatalysis
Eslamibidgoli, M. J., Huang, J., Kadyk, T., Malek, A., & Eikerling, M. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.06.004 · Cited by 83
Metadata
- Authors
- Vlassiouk, I., Smirnov, S., & Siwy, Z.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-06-18
- Volume
- 8
- Issue
- 7
- Pages
- 1978-1985
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2092525061
- Cited by
- 456
- References
- 0
- FWCI
- 11.72
- Type
- journal article
- Language
- en
- Open access
- closed
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