The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Reversible Basal Plane Hydrogenation of Graphene
Open accessAbstract
We report the chemical reaction of single-layer graphene with hydrogen atoms, generated in situ by electron-induced dissociation of hydrogen silsesquioxane (HSQ). Hydrogenation, forming sp3 C--H functionality on the basal plane of graphene, proceeds at a higher rate for single than for double layers, demonstrating the enhanced chemical reactivity of single sheet graphene. The net H atom sticking probability on single layers at 300 K is at least 0.03, which exceeds that of double layers by at least a factor of 15. Chemisorbed hydrogen atoms, which give rise to a prominent Raman D band, can be detached by thermal annealing at 100-200 degrees C. The resulting dehydrogenated graphene is "activated" when photothermally heated it reversibly binds ambient oxygen, leading to hole doping of the graphene. This functionalization of graphene can be exploited to manipulate electronic and charge transport properties of graphene devices.
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Cites
Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Experimental observation of the quantum Hall effect and Berry's phase in graphene
Zhang, Y., Tan, Y.-W., Stormer, H. L., & Kim, P. (2005) · Nature · doi:10.1038/nature04235 · Cited by 13,435
Self-citationGraphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
Cited by
Quantum interference and Klein tunnelling in graphene heterojunctions
Young, A. F., & Kim, P. (2009) · Nature Physics · doi:10.1038/nphys1198 · Cited by 1,183
Self-citationConnecting Dopant Bond Type with Electronic Structure in N-Doped Graphene
Schiros, T., Nordlund, D., Pálová, L., Prezzi, D., Zhao, L., Kim, K. S., Wurstbauer, U., Gutiérrez, C., Delongchamp, D., Jaye, C., et al. (2012) · Nano Letters · doi:10.1021/nl301409h · Cited by 540
Self-citationPhotochemical Reactivity of Graphene
Liu, H., Ryu, S., Chen, Z., Steigerwald, M. L., Nuckolls, C., & Brus, L. E. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9043906 · Cited by 371
Self-citationMicrobial reduction of graphene oxide by Shewanella
Wang, G., Qian, F., Saltikov, C. W., Jiao, Y., & Li, Y. (2011) · Nano Research · doi:10.1007/s12274-011-0112-2 · Cited by 361
Chemistry Makes Graphene beyond Graphene
Liao, L., Peng, H., & Liu, Z. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5048297 · Cited by 319
Metadata
- Authors
- Ryu, S., Han, M. Y., Maultzsch, J., Heinz, T. F., Kim, P., Steigerwald, M. L., & Brus, L. E.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-18
- Volume
- 8
- Issue
- 12
- Pages
- 4597-4602
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1997159984
- Cited by
- 551
- References
- 3
- FWCI
- 25.26
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
