The DOI matches its Crossref record.
A Comparison Study of the Catalytic Properties of Au-Based Nanocages, Nanoboxes, and Nanoparticles
Abstract
We have evaluated the catalytic properties of Au-based nanostructures (including nanocages, nanoboxes, and solid nanoparticles) using a model reaction based on the reduction of p-nitrophenol by NaBH(4). From the average reaction rate constants at three different temperatures, we determined the activation energy, the entropy of activation, and the pre-exponential factor for each type of Au nanostructure. The kinetic data indicate that the Au-based nanocages are catalytically more active than both the nanoboxes and nanoparticles probably due to their extremely thin but electrically continuous walls, the high content of Au, and the accessibility of both inner and outer surfaces through the pores in the walls. In addition, a compensation effect was observed in this Au-based catalytic system, which can be primarily interpreted by a model based on kinetic regime switching.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Xia, X., Wang, Y., Ruditskiy, A., & Xia, Y. (2013) · Advanced Materials · doi:10.1002/adma.201302820 · Cited by 1,019
Self-citationHe, R., Wang, Y.-C., Wang, X., Wang, Z., Liu, G., Zhou, W., Wen, L., Li, Q., Wang, X., Chen, X., et al. (2014) · Nature Communications · doi:10.1038/ncomms5327 · Cited by 344
Self-citationRu Nanoframes with an fcc Structure and Enhanced Catalytic Properties
Ye, H., Wang, Q., Catalano, M., Lu, N., Vermeylen, J., Kim, M. J., Liu, Y., Sun, Y., & Xia, X. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b00607 · Cited by 221
Face the Edges: Catalytic Active Sites of Nanomaterials
Ni, B., & Wang, X. (2015) · Advanced Science · doi:10.1002/advs.201500085 · Cited by 219
Metadata
- Authors
- Zeng, J., Zhang, Q., Chen, J., & Xia, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-11-23
- Volume
- 10
- Issue
- 1
- Pages
- 30-35
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2149262099
- Cited by
- 823
- References
- 0
- FWCI
- 19.63
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A Comparison Study of the Catalytic Properties of Au-Based Nanocages, Nanoboxes, and Nanoparticles. https://app.cochat.ai/papers/10.1021/nl903062e
- The paper
- Zeng, J., Zhang, Q., Chen, J., & Xia, Y. (2010). A Comparison Study of the Catalytic Properties of Au-Based Nanocages, Nanoboxes, and Nanoparticles. Nano Letters. https://doi.org/10.1021/nl903062e
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
