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Self-Assembly of All-Conjugated Poly(3-alkylthiophene) Diblock Copolymer Nanostructures from Mixed Selective Solvents
Abstract
The use of mixed selective solvents provides an effective means to control self-assembly of the all-conjugated diblock copolymer poly(3-butylthiophene)-b-poly(3-hexylthiophene) (P3BHT) into nanostructured morphologies. The solvent and temperature effects on the self-assembly of P3BHT during cooling and subsequent crystallization were explored for the first time. Depending on the poor/good solvent ratio (i.e., anisole/chloroform), P3BHT chains experience different kinetic pathways, yielding nanowires at a low anisole/chloroform ratio (< or =2:1), and nanorings coexisted with some nanowires at a high anisole/chloroform ratio (> or =6:1). The nanowires are formed as a direct consequence of strong interchain pi-pi stacking, while the formation of nanorings is governed by solvophobic interactions between conjugated blocks and the poor solvent anisole to minimize the unfavorable contacts between the P3BT block ( approximately 50 degrees C) and later P3HT (below 35 degrees C) block and anisole.
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Metadata
- Authors
- He, M., Zhao, L., Wang, J., Han, W., Yang, Y., Qiu, F., & Lin, Z.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-05-14
- Volume
- 4
- Issue
- 6
- Pages
- 3241-3247
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1977107382
- Cited by
- 164
- References
- 0
- FWCI
- 9.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, M., Zhao, L., Wang, J., Han, W., Yang, Y., Qiu, F., & Lin, Z. (2010). Self-Assembly of All-Conjugated Poly(3-alkylthiophene) Diblock Copolymer Nanostructures from Mixed Selective Solvents. ACS Nano. https://doi.org/10.1021/nn100543w
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