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High-Energy MnO2 Nanowire/Graphene and Graphene Asymmetric Electrochemical Capacitors
Abstract
In order to achieve high energy and power densities, we developed a high-voltage asymmetric electrochemical capacitor (EC) based on graphene as negative electrode and a MnO(2) nanowire/graphene composite (MGC) as positive electrode in a neutral aqueous Na(2)SO(4) solution as electrolyte. MGC was prepared by solution-phase assembly of graphene sheets and α-MnO(2) nanowires. Such aqueous electrolyte-based asymmetric ECs can be cycled reversibly in the high-voltage region of 0-2.0 V and exhibit a superior energy density of 30.4 Wh kg(-1), which is much higher than those of symmetric ECs based on graphene//graphene (2.8 Wh kg(-1)) and MGC//MGC (5.2 Wh kg(-1)). Moreover, they present a high power density (5000 W kg(-1) at 7.0 Wh kg(-1)) and acceptable cycling performance of ∼79% retention after 1000 cycles. These findings open up the possibility of graphene-based composites for applications in safe aqueous electrolyte-based high-voltage asymmetric ECs with high energy and power densities.
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Metadata
- Authors
- Wu, Z.-S., Ren, W., Wang, D.-W., Li, F., Liu, B., & Cheng, H.-M.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-21
- Volume
- 4
- Issue
- 10
- Pages
- 5835-5842
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2014025437
- Cited by
- 1,517
- References
- 40
- FWCI
- 36.96
- Type
- journal article
- Language
- en
- Open access
- closed
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