Synthesis of Ultrathin MnO 2 Nanowire-Intercalated 2D-MXenes for High-Performance Hybrid Supercapacitors
Abstract
Recently, the MXene itself and its composites with various metal oxides have shown excellent electrochemical performance due to the presence of multiple oxidation states. However, the restacking of MXene layers and poor electrical conductivity of metal oxides are major bottlenecks in their effective electrochemical transport, when they are applied individually. Herein, we report a novel manganese oxide/MXene (MnO 2 /MXene) composite material to overcome these critical issues. Sub-50 nm-thick MnO 2 nanowires (NWRs) were introduced inside the MXene to effectively stop the restacking as well as to increase the surface area of the supercapacitor (SC) electrode material. The special control on the thickness of NWRs is not only providing an opportunity to adjust them inside the MXene layers but also giving a high surface area. Electrochemical studies suggested that the MnO 2 /MXene composite behaves as an excellent electrode material for hybrid SCs, as compared to individual MXene and MnO 2 . Maximum specific capacitance ( C sp ) of MXene, MnO 2 NWRs, and MnO 2 /MXene composite was observed to be about 527.8, 337.5, and 611.5 F/g, respectively. The calculated specific capacity of the MnO 2 /MXene composite was about 489.5 C/g at 1 A/g, which shows better performance as an electrode material for energy storage devices. The synthesized electrode material demonstrated excellent capacitance retention of about 96% up to 1000 cycles.
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The FTIR spectrum of NCSe@MGA is much similar to that of NCSe@GA.
“FTIR spectrum of NCSe@MGA was much similar to NCSe@GA [57].”
XRD peaks in NCSe@GA and NCSe@MGA show slight forward shifting after composite fabrication.
“Besides, XRD peaks in NCSe@GA and NCSe@MGA showed slight forward shifting after fabrication of composite [57].”
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- Authors
- Mahmood, M., Rasheed, A., Ayman, I., Rasheed, T., Munir, S., Ajmal, S., Agboola, P. O., Warsi, M. F., & Shahid, M.
- Affiliations
- Islamia University of Bahawalpur (PK)
- King Saud University (SA)
- University of Hafr Al-Batin (SA)
- Corresponding author
- Warsi, Muhammad Farooq
- Shahid, Muhammad
- ORCID
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-01-26
- Volume
- 35
- Issue
- 4
- Pages
- 3469-3478
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W3122549511
- Cited by
- 253
- References
- 52
- Citations by year
- 2026: 40 · 2025: 50 · 2024: 83 · 2023: 45 · 2022: 25 · 2021: 10
- FWCI
- 12.38
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Energy & Fuels (publishedVersion)
- Funders
- Higher Education Commision, Pakistan (6276/Punjab/NRPU/R&D/HEC)
- King Saud University (RSP 2020/163)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- MXene, MnO2 nanowires, hybrid supercapacitors, specific capacitance, cycling stability, electrode materials, energy storage, ultrathin nanowires
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