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Nitrogen-Promoted Self-Assembly of N-Doped Carbon Nanotubes and Their Intrinsic Catalysis for Oxygen Reduction in Fuel Cells
Abstract
Nitrogen atoms were found to exhibit a strong ability to promote the self-assembly of nitrogen-doped carbon nanotubes (NCNTs) from gaseous carbons, without an assistance of metal atoms. On the basis of this discovery, pure metal-free CNTs with a nitrogen-doping level as high as 20 atom % can be directly synthesized using melamine as a C/N precursor. This offers a novel pathway for carbon nanotube synthesis. Furthermore, the metal-free and intact characteristics of the NCNT samples facilitate a clear verification of the intrinsic catalytic ability of NCNTs. The results show that the NCNTs intrinsically display excellent catalytic activity for oxygen reduction in fuel cells, comparable to traditional platinum-based catalysts. More notably, they exhibit outstanding stability, selectivity, and resistance to CO poisoning, much superior to the platinum-based catalysts.
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Citations
Cites
Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis
Pels, J. R., Kapteijn, F., Moulijn, J. A., Zhu, Q., & Thomas, K. M. (1995) · Carbon · doi:10.1016/0008-6223(95)00154-6 · Cited by 2,041
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Cited by
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Heterogeneous nanocarbon materials for oxygen reduction reaction
Wang, D.-W., & Su, D. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43463j · Cited by 1,018
Zhong, H., Wang, J., Zhang, Y., Xu, W., Xing, W., Xu, D., Zhang, Y., & Zhang, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408990 · Cited by 938
Carbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
Nitrogen‐Doped Carbon Nanotube Aerogels for High‐Performance ORR Catalysts
Du, R., Zhang, N., Zhu, J., Wang, Y., Xu, C., Hu, Y., Mao, N., Xu, H., Duan, W., Zhuang, L., et al. (2015) · Small · doi:10.1002/smll.201500587 · Cited by 121
Metadata
- Authors
- Wang, Z., Jia, R., Zheng, J., Zhao, J., Li, L., Song, J., & Zhu, Z.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-02-10
- Volume
- 5
- Issue
- 3
- Pages
- 1677-1684
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2113436136
- Cited by
- 229
- References
- 2
- FWCI
- 11.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Z., Jia, R., Zheng, J., Zhao, J., Li, L., Song, J., & Zhu, Z. (2011). Nitrogen-Promoted Self-Assembly of N-Doped Carbon Nanotubes and Their Intrinsic Catalysis for Oxygen Reduction in Fuel Cells. ACS Nano. https://doi.org/10.1021/nn1030127
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