The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles
Abstract
Nanoparticles of NaAlH(4) have been infiltrated in nanoporous carbon aerogel with TiCl(3) nanoparticles in order to explore possible synergetic effects between nanoconfinement and a functionalized catalytic scaffold. Resorcinol formaldehyde carbon aerogels with an average pore size of 17 nm and total pore volume of 1.26 mL/g were infiltrated with TiCl(3) to obtain an aerogel doped with 3.0 wt % TiCl(3) nanoparticles. NaAlH(4) was melt-infiltrated into the functionalized carbon aerogel at 189 °C and p(H(2)) ∼ 186-199 bar. Energy-dispersive spectrometry (EDS) combined with focused ion beam (FIB) techniques revealed the presence of Na, Al, Ti, and Cl inside the aerogel scaffold material. The infiltrated NaAlH(4) was X-ray amorphous, whereas (27)Al magic-angle spinning (MAS) NMR spectroscopy confirmed the presence of nanoconfined NaAlH(4). Temperature-programmed desorption mass spectroscopy (TPD-MS) and Sieverts' measurements demonstrated significantly improved hydrogen desorption kinetics for this new nanoconfined NaAlH(4)-TiCl(3) material as compared to nanoconfined NaAlH(4) without the catalysts TiCl(3) and to bulk ball-milled samples of NaAlH(4)-TiCl(3). We find that the onset temperature for hydrogen release was close to room temperature (T(onset) = 33 °C), and the hydrogen release rate reached a maximum value at 125 °C, which demonstrates favorable synergetic effects between nanoconfinement and catalyst addition.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The technological challenge of powders such as poor recoverability and reproducibility significantly restricts the industrial applicability of MOFs.
“Moreover, the technological challenge of powders such as poor recoverability and reproducibility significantly restricts the industrial applicability of MOFs.46−50”
From Bimetallic (Co/Ni) MOF-Derived CoNiP Hierarchically Porous Carbon Monolithic Aerogel for the Hydrolysis of Ammonia Borane (2024) · cites this paper as [50]
Citations
Cites
Hydrogen-storage materials for mobile applications
Schlapbach, L., & Züttel, A. (2001) · Nature · doi:10.1038/35104634 · Cited by 8,865
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,412
Metal hydride materials for solid hydrogen storage: A review
SAKINTUNA, B., LAMARIDARKRIM, F., & HIRSCHER, M. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.11.022 · Cited by 3,715
Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials
Bogdanović, B., & Schwickardi, M. (1997) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(96)03049-6 · Cited by 1,824
Chemical and Physical Solutions for Hydrogen Storage
Eberle, U., Felderhoff, M., & Schüth, F. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806293 · Cited by 1,671
Preparation and Properties of Resorcinol–Formaldehyde Organic and Carbon Gels
Al‐Muhtaseb, S. A., & Ritter, J. A. (2003) · Advanced Materials · doi:10.1002/adma.200390020 · Cited by 1,035
New approaches to hydrogen storage
Graetz, J. (2008) · Chemical Society Reviews · doi:10.1039/b718842k · Cited by 1,010
Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane
Gutowska, A., Li, L., Shin, Y., Wang, C. M., Li, X. S., Linehan, J. C., Smith, R. S., Kay, B. D., Schmid, B., Shaw, W. J., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462602 · Cited by 794
Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials
Bogdanović, B., Brand, R. A., Marjanović, A., Schwickardi, M., & Tölle, J. (2000) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(99)00663-5 · Cited by 709
Size effects on the hydrogen storage properties of nanostructured metal hydrides: A review
Bérubé, V., Radtke, G., Dresselhaus, M. S., & Chen, G. (2007) · International Journal of Energy Research · doi:10.1002/er.1284 · Cited by 651
Nanocrystalline metal hydrides
Załuski, L., Załuska, A., & Ström‐Olsen, J. O. (1997) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(96)02985-4 · Cited by 480
Enhanced Hydrogen Storage Kinetics of LiBH4in Nanoporous Carbon Scaffolds
Gross, A. F., Vajo, J. J., Atta, S. L. V., & Olson, G. L. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp711066t · Cited by 439
Nanosizing and Nanoconfinement: New Strategies Towards Meeting Hydrogen Storage Goals
de Jongh, P. E., & Adelhelm, P. (2010) · ChemSusChem · doi:10.1002/cssc.201000248 · Cited by 397
Effect of Ti-catalyst content on the reversible hydrogen storage properties of the sodium alanates
Sandrock, G. D., Gross, K., & Thomas, G. J. (2002) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(01)02014-x · Cited by 392
Li, J., Wang, X., Huang, Q., Gamboa, S. A., & Sebastian, P. J. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.09.045 · Cited by 369
Bogdanović, B., Felderhoff, M., Kaskel, S., Pommerin, A., Schlichte, K., & Schüth, F. (2003) · Advanced Materials · doi:10.1002/adma.200304711 · Cited by 294
Nanoconfined hydrides for energy storage
Nielsen, T. K., Besenbacher, F., & Jensen, T. R. (2011) · Nanoscale · doi:10.1039/c0nr00725k · Cited by 291
Self-citationConfinement of MgH2Nanoclusters within Nanoporous Aerogel Scaffold Materials
Nielsen, T. K., Manickam, K., Hirscher, M., Besenbacher, F., & Jensen, T. R. (2009) · ACS Nano · doi:10.1021/nn901072w · Cited by 262
Self-citationHard-Templating Pathway To Create Mesoporous Magnesium Oxide
Li, W., Lu, A., Weidenthaler, C., & Schüth, F. (2004) · Chemistry of Materials · doi:10.1021/cm048759n · Cited by 248
Carbon Nanomaterials as Catalysts for Hydrogen Uptake and Release in NaAlH4
Berseth, P. A., Harter, A. G., Zidan, R., Blomqvist, A., Araujo, C. M., Scheicher, R. H., Ahuja, R., & Jena, P. (2009) · Nano Letters · doi:10.1021/nl803498e · Cited by 220
Altered thermodynamic and kinetic properties of MgH2 infiltrated in microporous scaffold
Zhao‐Karger, Z., Hu, J., Roth, A., Wang, D., Kübel, C., Lohstroh, W., & Fichtner, M. (2010) · Chemical Communications · doi:10.1039/c0cc03072d · Cited by 218
Hydrogen Storage Properties of Space-Confined NaAlH4 Nanoparticles in Ordered Mesoporous Silica
Zheng, S., Fang, F., Zhou, G., Chen, G., Ouyang, L., Zhu, M. H., & Sun, D. (2008) · Chemistry of Materials · doi:10.1021/cm8002063 · Cited by 195
A Reversible Nanoconfined Chemical Reaction
Nielsen, T. K., Boesenberg, U., Gosalawit, R., Dornheim, M., Cerenius, Y., Besenbacher, F., & Jensen, T. R. (2010) · ACS Nano · doi:10.1021/nn1006946 · Cited by 192
Self-citationPreparation and Characterization of Nanomaterials for Sustainable Energy Production
Liu, C., Burghaus, U., Besenbacher, F., & Wang, Z. L. (2010) · ACS Nano · doi:10.1021/nn102420c · Cited by 191
Self-citationConfinement of NaAlH4in Nanoporous Carbon: Impact on H2Release, Reversibility, and Thermodynamics
Gao, J., Adelhelm, P., Verkuijlen, M. H. W., Rongeat, C., Herrich, M., van Bentum, P. J. M., Gutfleisch, O., Kentgens, A. P. M., de Jong, K. P., & de Jongh, P. E. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp910511g · Cited by 171
Versatile in situ powder X-ray diffraction cells for solid–gas investigations
Jensen, T. R., Nielsen, T. K., Filinchuk, Y. E., Jørgensen, J., Cerenius, Y., Gray, E. M., & Webb, C. J. (2010) · Journal of Applied Crystallography · doi:10.1107/s0021889810038148 · Cited by 162
Self-citationHydrogen in amorphous and nanocrystalline metals
Kirchheim, R., Mütschele, T., Kieninger, W., Gleiter, H., Birringer, R., & Köble, T. (1988) · Materials Science and Engineering · doi:10.1016/0025-5416(88)90377-1 · Cited by 162
Synchrotron X-ray and neutron diffraction studies of NaAlH4 containing Ti additives
Brinks, H. W., Jensen, C. M., Srinivasan, S. S., Hauback, B. C., Blanchard, D., & Murphy, K. (2004) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2003.12.024 · Cited by 160
Bogdanović, B., Felderhoff, M., Germann, M., Härtel, M., Pommerin, A., Schüth, F., Weidenthaler, C., & Zibrowius, B. (2003) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(02)00953-2 · Cited by 153
Bogdanović, B., & Schwickardi, M. (2001) · Applied Physics A · doi:10.1007/s003390100774 · Cited by 131
Kim, H., Karkamkar, A., Autrey, T. S., Chupas, P. J., & Proffen, T. E. (2009) · Journal of the American Chemical Society · doi:10.1021/ja904901d · Cited by 94
Thermodynamic Effects in Nanoscale NaAlH 4
Lohstroh, W., Roth, A., Hahn, H., & Fichtner, M. (2010) · ChemPhysChem · doi:10.1002/cphc.200900767 · Cited by 91
The kinetic enhancement of hydrogen cycling in NaAlH4by melt infusion into nanoporous carbon aerogel
Stephens, R. D., Gross, A. F., Atta, S. L. V., Vajo, J. J., & Pinkerton, F. E. (2009) · Nanotechnology · doi:10.1088/0957-4484/20/20/204018 · Cited by 90
Effect of Particle Size on Hydrogen Release from Sodium Alanate Nanoparticles
Mueller, T., & Ceder, G. (2010) · ACS Nano · doi:10.1021/nn101224j · Cited by 90
Comprehensive Study of Melt Infiltration for the Synthesis of NaAlH4/C Nanocomposites
Adelhelm, P., Gao, J., Verkuijlen, M. H. W., Rongeat, C., Herrich, M., van Bentum, P. J. M., Gutfleisch, O., Kentgens, A. P. M., de Jong, K. P., & de Jongh, P. E. (2010) · Chemistry of Materials · doi:10.1021/cm902681d · Cited by 82
Novel catalytic effects of fullerene for LiBH4hydrogen uptake and release
Wellons, M. S., Berseth, P. A., & Zidan, R. (2009) · Nanotechnology · doi:10.1088/0957-4484/20/20/204022 · Cited by 72
Adelhelm, P., de Jong, K. P., & de Jongh, P. E. (2009) · Chemical Communications · doi:10.1039/b910461e · Cited by 69
Paolone, A., Palumbo, O., Rispoli, P., Cantelli, R., Autrey, T. S., & Karkamkar, A. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902341s · Cited by 68
Verkuijlen, M. H. W., Gao, J., Adelhelm, P., van Bentum, P. J. M., de Jongh, P. E., & Kentgens, A. P. M. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp911228x · Cited by 58
Pitt, M. P., Vullum, P. E., Sørby, M. H., Sulic, M., Jensen, C. M., Walmsley, J. C., Holmestad, R., & Hauback, B. C. (2008) · Acta Materialia · doi:10.1016/j.actamat.2008.05.037 · Cited by 32
Mechanochemical synthesis and XPS analysis of sodium alanate with different additives
Rongeat, C., Llamas‐Jansa, I., Oswald, S., Schultz, L., & Gutfleisch, O. (2009) · Acta Materialia · doi:10.1016/j.actamat.2009.07.053 · Cited by 32
Kellberg, L., Bildsøe, H., & JAKOBSEN, H. J. (1990) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39900001294 · Cited by 22
Tian, H., Buckley, C. E., Paskevicius, M., & Wang, S. (2010) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2010.10.028 · Cited by 16
Flagged first, then by citations
Cited by
Sorted by citations
Nanostructured Metal Hydrides for Hydrogen Storage
Schneemann, A., White, J. L., Kang, S., Jeong, S., Wan, L. F., Cho, E. S., Heo, T. W., Prendergast, D., Urban, J. J., Wood, B. C., et al. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00313 · Cited by 830
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Zhang, X. S., Liu, Y., Ren, Z., Zhang, X., Hu, J., Huang, Z., Lu, Y., Gao, M., & Pan, H. (2020) · Energy & Environmental Science · doi:10.1039/d0ee03160g · Cited by 514
Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art
Lai, Q., Paskevicius, M., Sheppard, D. A., Buckley, C. E., Thornton, A. W., Hill, M. R., Gu, Q., Mao, J., Huang, Z., Liu, H., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500231 · Cited by 420
High capacity hydrogen storage: Basic aspects, new developments and milestones
Pukazhselvan, D., Kumar, V., & Singh, S. K. (2012) · Nano Energy · doi:10.1016/j.nanoen.2012.05.004 · Cited by 275
Tailoring properties of borohydrides for hydrogen storage: A review
Rude, L. H., Nielsen, T. K., Ravnsbæk, D. B., Boesenberg, U., Ley, M. B., Richter, B., Arnbjerg, L. M., Dornheim, M., Filinchuk, Y. E., Besenbacher, F., et al. (2011) · physica status solidi (a) · doi:10.1002/pssa.201001214 · Cited by 269
Self-citationHydrogen storage in light-metal based systems: A review
Ouyang, L., Chen, K., Jiang, J., Yang, X., & Zhu, M. (2020) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2020.154597 · Cited by 249
Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage
Møller, K. T., Sheppard, D. A., Ravnsbæk, D. B., Buckley, C. E., Akiba, E., Li, H., & Jensen, T. R. (2017) · Energies · doi:10.3390/en10101645 · Cited by 237
Self-citationComplex hydrides for energy storage
Milanese, C., Jensen, T. R., Hauback, B. C., Pistidda, C., Dornheim, M., Yang, H., Lombardo, L., Züttel, A., Filinchuk, Y. E., Ngene, P., et al. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.11.208 · Cited by 217
Self-citationEnvironmental Applications of Engineered Materials with Nanoconfinement
Zhang, S., Hedtke, T., Zhou, X., Elimelech, M., & Kim, J. (2021) · ACS ES&T Engineering · doi:10.1021/acsestengg.1c00007 · Cited by 179
Stavila, V., Bhakta, R. K., Alam, T. M., Majzoub, E. H., & Allendorf, M. D. (2012) · ACS Nano · doi:10.1021/nn304514c · Cited by 171
de Jongh, P. E., & Eggenhuisen, T. M. (2013) · Advanced Materials · doi:10.1002/adma.201301912 · Cited by 164
A Bird's Eye view on process and engineering aspects of hydrogen storage
Sreedhar, I., Kamani, K. M., Kamani, B. M., Reddy, B. M., & Venugopal, A. (2018) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2018.04.028 · Cited by 146
Hydrogen storage in complex hydrides: past activities and new trends
Dematteis, E. M., Amdisen, M. B., Autrey, T. S., Barale, J., Bowden, M., Buckley, C. E., Cho, Y. W., Deledda, S., Dornheim, M., de Jongh, P. E., et al. (2022) · Progress in Energy · doi:10.1088/2516-1083/ac7499 · Cited by 130
Self-citationNanoconfined light metal hydrides for reversible hydrogen storage
de Jongh, P. E., Allendorf, M. D., Vajo, J. J., & Zlotea, C. (2013) · MRS Bulletin · doi:10.1557/mrs.2013.108 · Cited by 124
Desai, F. J., Uddin, M. N., Rahman, M. M., & Asmatulu, R. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.04.029 · Cited by 124
Single and Polystorage Technologies for Renewable-Based Hybrid Energy Systems
Abdin, Z., & Khalilpour, K. R. (2018) · Elsevier eBooks · doi:10.1016/b978-0-12-813306-4.00004-5 · Cited by 112
Enhanced hydrogen desorption from Mg(BH4)2 by combining nanoconfinement and a Ni catalyst
Wahab, M. A., Jia, Y. A., Yang, D., Zhao, H., & Yao, X. (2013) · Journal of Materials Chemistry A · doi:10.1039/c2ta00899h · Cited by 103
Complex and liquid hydrides for energy storage
Callini, E., Atakli, Z. Ö. K., Hauback, B. C., Orimo, S., Jensen, C. M., Dornheim, M., Grant, D. M., Cho, Y. W., Chen, P., Hjörvarsson, B., et al. (2016) · Applied Physics A · doi:10.1007/s00339-016-9881-5 · Cited by 98
Self-citationDuan, C., Tian, Y., Wang, X., Wu, M., Fu, D., Zhang, Y., Lv, W., Su, Z., Xue, Z., & Wu, Y. (2022) · Renewable Energy · doi:10.1016/j.renene.2022.01.048 · Cited by 98
Theoretical study of C60as catalyst for dehydrogenation in LiBH4
Scheicher, R. H., Li, S., Araujo, C. M., Blomqvist, A., Ahuja, R., & Jena, P. (2011) · Nanotechnology · doi:10.1088/0957-4484/22/33/335401 · Cited by 92
Nanoconfined LiBH4 and Enhanced Mobility of Li+ and BH4– Studied by Solid-State NMR
Verkuijlen, M. H. W., Ngene, P., de Kort, D. W., Barré, C., Nale, A., van Eck, E. R. H., van Bentum, P. J. M., de Jongh, P. E., & Kentgens, A. P. M. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp306175b · Cited by 91
RETRACTED: Solar hydrogen hybrid energy systems for off-grid electricity supply: A critical review
Abdin, Z., Webb, C. J., & Gray, E. M. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.08.011 · Cited by 87
RetractedKudiiarov, V. N., Lyu, J., Semyonov, O., Lider, A. M., Chaemchuen, S., & Verpoort, F. (2021) · Applied Materials Today · doi:10.1016/j.apmt.2021.101208 · Cited by 83
Nanostructured light metal hydride: Fabrication strategies and hydrogen storage performance
Liu, Y., Zhang, W., Zhang, X. S., Yang, L., Huang, Z., Fang, F., Sun, W., Gao, M., & Pan, H. (2023) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2023.113560 · Cited by 80
Innovations in hydrogen storage materials: Synthesis, applications, and prospects
Osman, A. I., Ayati, A., Farrokhi, M., Khadempir, S., Rajabzadeh, A. R., Farghali, M. R. F., Krivoshapkin, P. V., Tanhaei, B., Rooney, D. W., & Yap, P. (2024) · Journal of Energy Storage · doi:10.1016/j.est.2024.112376 · Cited by 80
Improved Hydrogen Storage Properties of LiBH4 Destabilized by in Situ Formation of MgH2 and LaH3
Zhou, Y., Liu, Y., Wu, W., Zhang, Y., Gao, M., & Pan, H. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2101573 · Cited by 79
Transforming MOFs for Energy Applications Using the Guest@MOF Concept
Ullman, A. M., Brown, J. W., Foster, M. E., Léonard, F., Leong, K., Stavila, V., & Allendorf, M. D. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b00909 · Cited by 78
Hydrogen storage properties of nanoconfined LiBH4–Ca(BH4)2
Javadian, P., Sheppard, D. A., Buckley, C. E., & Jensen, T. R. (2014) · Nano Energy · doi:10.1016/j.nanoen.2014.09.035 · Cited by 73
Self-citationChong, L., Zeng, X., Ding, W., Liu, D., & Zou, J. (2015) · Advanced Materials · doi:10.1002/adma.201500831 · Cited by 71
MgH2–Nb2O5 investigated by in situ synchrotron X-ray diffraction
Nielsen, T. K., & Jensen, T. R. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.06.082 · Cited by 66
Self-citationNanointerface Engineering of Metal Hydrides for Advanced Hydrogen Storage
Cho, Y., Cho, H. M., & Cho, E. S. (2023) · Chemistry of Materials · doi:10.1021/acs.chemmater.2c02628 · Cited by 64
Shao, J., Xiao, X., Fan, X., Zhang, L., Li, S., Ge, H., Wang, Q., & Chen, L. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp503127m · Cited by 64
Sodium alanate system for efficient hydrogen storage
Li, L., Xu, C., Chen, C., Wang, Y., Jiao, L., & Yuan, H. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.04.109 · Cited by 63
Nielsen, T. K., Javadian, P., Polański, M., Besenbacher, F., Bystrzycki, J., & Jensen, T. R. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3049982 · Cited by 62
Self-citationNanoconfined 2LiBH4–MgH2–TiCl3 in carbon aerogel scaffold for reversible hydrogen storage
Gosalawit–Utke, R., Milanese, C., Javadian, P., Jepsen, J., Laipple, D., Karmi, F., Puszkiel, J., Jensen, T. R., Marini, A., Klassen, T., et al. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.12.123 · Cited by 56
Self-citationChen, W., You, L., Xia, G., & Yu, X. (2020) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2020.11.052 · Cited by 56
Lai, Q., Wang, T., Sun, Y., & Aguey‐Zinsou, K. (2018) · Advanced Materials Technologies · doi:10.1002/admt.201700298 · Cited by 55
Cho, Y., Li, S., Snider, J. L., Marple, M. A. T., Strange, N. A., Sugar, J. D., Gabaly, F. E., Schneemann, A., Kang, S., Kang, M., et al. (2021) · ACS Nano · doi:10.1021/acsnano.1c02079 · Cited by 53
Nanoconfined NaAlH 4 : prolific effects from increased surface area and pore volume
Nielsen, T. K., Javadian, P., Polański, M., Besenbacher, F., Bystrzycki, J., Skibsted, J., & Jensen, T. R. (2013) · Nanoscale · doi:10.1039/c3nr03538g · Cited by 53
Self-citationZhang, H., Kong, Q., Hu, S. J., Zhang, D., Chen, H., Xu, C. C., Li, B., Fan, Y., & Liu, B. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c06444 · Cited by 51
Anomalous H2 Desorption Rate of NaAlH4 Confined in Nitrogen-Doped Nanoporous Carbon Frameworks
Carr, C. L., Jayawardana, W., Zou, H., White, J. L., Gabaly, F. E., Conradi, M. S., Stavila, V., Allendorf, M. D., & Majzoub, E. H. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b00305 · Cited by 49
Two-dimensional C@TiO2/Ti3C2 composite with superior catalytic performance for NaAlH4
Yuan, Z., Fan, Y., Chen, Y., Liu, X., Liu, B., & Han, S. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.05.243 · Cited by 48
Significantly improved hydrogen storage properties of NaAlH4 catalyzed by Ce-based nanoparticles
Fan, X., Xiao, X., Chen, L., Zhang, L., Shao, J., Li, S., Ge, H., & Wang, Q. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta11860f · Cited by 48
Duan, C., Wu, M., Cao, Y., Fu, D., Zhang, Y., Su, Z., Sun, Z., & Wu, Y. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01938d · Cited by 47
Thermodynamics and kinetics of NaAlH4 nanocluster decomposition
Bhakta, R. K., Maharrey, S. P., Stavila, V., Highley, A., Alam, T. M., Majzoub, E. H., & Allendorf, M. D. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp40196g · Cited by 46
Size effect on hydrogen storage properties of NaAlH4 confined in uniform porous carbons
Fan, X., Xiao, X., Shao, J., Zhang, L., Li, S., Ge, H., Wang, Q., & Chen, L. (2013) · Nano Energy · doi:10.1016/j.nanoen.2013.03.021 · Cited by 46
Stabilization of NaZn(BH 4 ) 3 via nanoconfinement in SBA-15 towards enhanced hydrogen release
Xia, G., Li, L., Guo, Z., Gu, Q., Guo, Y., Yu, X., Liu, H., & Liu, Z. (2012) · Journal of Materials Chemistry A · doi:10.1039/c2ta00195k · Cited by 42
Evolution of the active species and catalytic mechanism of Ti doped NaAlH 4 for hydrogen storage
Xiong, R., Sang, G., Zhang, G., Yan, X., Li, P., Yao, Y., Luo, D., Chen, C., & Tang, T. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2016.12.105 · Cited by 42
Synthesis of NaAlH4/Al composites and their applications in hydrogen storage
Ianni, E., Sofianos, M. V., Rowles, M. R., Sheppard, D. A., Humphries, T. D., & Buckley, C. E. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.07.072 · Cited by 41
Wahab, M. A., & Beltramini, J. N. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.09.010 · Cited by 41
Confined NaAlH 4 nanoparticles inside CeO 2 hollow nanotubes towards enhanced hydrogen storage
Gao, Q., Xia, G., & Yu, X. (2017) · Nanoscale · doi:10.1039/c7nr03512h · Cited by 39
Nanoconfinement degradation in NaAlH4/CMK-1
Chumphongphan, S., Filsø, U., Paskevicius, M., Sheppard, D. A., Jensen, T. R., & Buckley, C. E. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.05.087 · Cited by 38
Self-citationUtilizing Nanostructured Materials for Hydrogen Generation, Storage, and Diverse Applications
Saeed, M., Marwani, H. M., Shahzad, U., Asiri, A. M., Hussain, I., & Rahman, M. M. (2023) · Chemistry - An Asian Journal · doi:10.1002/asia.202300593 · Cited by 38
Zhao, Y., Han, M., Wang, H., Chen, C., & Chen, J. (2016) · Inorganic Chemistry Frontiers · doi:10.1039/c6qi00200e · Cited by 37
Zhang, X., Liu, Y., Pang, Y., Gao, M., & Pan, H. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta14202g · Cited by 37
Wahab, M. A., Young, D. J., Karim, A., Fawzia, S., & Beltramini, J. N. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2016.09.098 · Cited by 35
Rueda, M., Sanz-Moral, L. M., & Martín, Á. (2018) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2018.02.010 · Cited by 35
Xia, G., Meng, Q. G., Guo, Z., Gu, Q., Liu, H., Liu, Z., & Yu, X. (2013) · Acta Materialia · doi:10.1016/j.actamat.2013.07.066 · Cited by 33
Hexafluoroisopropyl alcohol as a new solvent for aerogels preparation
Лермонтов, С. А., Malkova, A. N., Yurkova, L. L., Straumal, E. A., Gubanova, N. N., Baranchikov, A. E., Smirnov, M., Tarasov, V., Buznik, V. M., & Ivanov, V. K. (2014) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2014.02.011 · Cited by 32
Mao, Y., Zuo, W., Wu, C., Ma, W., Tian, Y. P., Zhang, J., Li, L., Zhan, W., & Qiu, J. (2025) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2025.144762 · Cited by 31
Xu, X., Zang, L., Zhao, Y., Zhao, Y., Wang, Y., & Jiao, L. (2017) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.05.047 · Cited by 31
Effect of carbon nanoscaffolds on hydrogen storage performance of magnesium hydride
Han, D. J., Bang, K. R., Cho, H. M., & Cho, E. S. (2020) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-020-0630-2 · Cited by 31
Xia, G., Chen, X., Zhou, C., Zhang, C., Li, D., Gu, Q., Guo, Z., Liu, H., Liu, Z., & Yu, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta00259a · Cited by 29
Hydrogen storage properties of activated carbon confined LiBH4 doped with CeF3 as catalyst
Zhou, H., Zhang, L., Gao, S., Liu, H., Xu, L., Wang, X., & Yan, M. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.06.193 · Cited by 29
Rajamani, A., Saravanan, V., Mohanapriya, S., & Shankar, R. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.10.170 · Cited by 28
Xia, G., Chen, X., Zhao, Y. C., Li, X., Guo, Z., Jensen, C. M., Gu, Q., & Yu, X. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02589 · Cited by 27
Methods to stabilize and destabilize ammonium borohydride
Nielsen, T. K., Karkamkar, A., Bowden, M., Besenbacher, F., Jensen, T. R., & Autrey, T. S. (2012) · Dalton Transactions · doi:10.1039/c2dt31591b · Cited by 26
Self-citationPinkerton, F. E. (2011) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2011.06.097 · Cited by 25
Arnbjerg, L. M., & Jensen, T. R. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.09.108 · Cited by 25
Self-citationXiong, R., Sang, G., Yan, X., Zhang, G., & Ye, X. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm31961f · Cited by 25
Zhang, X., Liu, Y., Wang, K., Li, Y., Gao, M., & Pan, H. (2015) · ChemSusChem · doi:10.1002/cssc.201501266 · Cited by 25
NaAlH4 confined in ordered mesoporous carbon
Minella, C. B., Lindemann, I., Nolis, P., Kießling, A., Baró, M. D., Klose, M., Giebeler, L., Rellinghaus, B., Eckert, J., Schultz, L., et al. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.04.103 · Cited by 25
Cyclic stability and structure of nanoconfined Ti-doped NaAlH 4
Paskevicius, M., Filsø, U., Karimi, F., Puszkiel, J., Pranzas, P. K., Pistidda, C., Hoell, A., Welter, E., Schreyer, A. G., Klassen, T., et al. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2015.12.185 · Cited by 24
Self-citationCatalyzed KSiH 3 as a reversible hydrogen storage material
Janot, R., Tang, W. S., Clémençon, D., & Chotard, J. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta07563k · Cited by 23
Hydrogen Desorption Properties of Bulk and Nanoconfined LiBH4-NaAlH4
Javadian, P., Sheppard, D. A., Buckley, C. E., & Jensen, T. R. (2016) · Crystals · doi:10.3390/cryst6060070 · Cited by 21
Self-citationNew Insights into the Thermodynamic Behavior of 2LiBH4–MgH2 Composite for Hydrogen Storage
Cova, F. H., Rönnebro, E. C. E., Choi, Y. J., Gennari, F. C., & Larochette, P. A. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b02047 · Cited by 21
Reversibility of LiBH4 Facilitated by the LiBH4–Ca(BH4)2 Eutectic
Javadian, P., Payandeh, S., Li, H., Sheppard, D. A., Buckley, C. E., & Jensen, T. R. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b06228 · Cited by 20
Self-citationHydrogen storage properties of eutectic metal borohydrides melt-infiltrated into porous Al scaffolds
Sofianos, M. V., Chaudhary, A., Paskevicius, M., Sheppard, D. A., Humphries, T. D., Dornheim, M., & Buckley, C. E. (2018) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2018.10.086 · Cited by 20
Do, H. W., Kim, H., & Cho, E. S. (2021) · RSC Advances · doi:10.1039/d1ra05111c · Cited by 19
Paving the Way to the Fuel of the Future—Nanostructured Complex Hydrides
Comanescu, C. C. (2022) · International Journal of Molecular Sciences · doi:10.3390/ijms24010143 · Cited by 18
A NaAlH4-Ca(BH4)2 composite system for hydrogen storage
Møller, K. T., Grinderslev, J. B., & Jensen, T. R. (2017) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2017.05.264 · Cited by 18
Self-citationXiong, R., Sang, G., Yan, X., Zhang, G., Ye, X., Jiang, C., & Luo, L. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.03.162 · Cited by 18
Kinetics of hydrogen release from dissolutions of ammonia borane in different ionic liquids
Valero‐Pedraza, M., Martín-Cortés, A., Navarrete, A., Bermejo, M. D., & Martín, Á. (2015) · Energy · doi:10.1016/j.energy.2015.08.106 · Cited by 18
Krebsz, M., Pasinszki, T., Sreenath, S., Andrews, J., & Ting, V. P. (2025) · Sustainable Energy & Fuels · doi:10.1039/d5se00950b · Cited by 16
Separation and characterization of the active species in Ti-doped NaAlH4
Xiong, R., Sang, G., Yan, X., Zhang, G., Xu, Q., & Zhang, H. (2012) · Chemical Communications · doi:10.1039/c2cc38553h · Cited by 16
Rueda, M., Sanz-Moral, L. M., & Martín, Á. (2014) · Crystal Growth & Design · doi:10.1021/cg500914j · Cited by 16
NaAlH4Nanoconfinement in a Mesoporous Carbon for Application in Lithium Ion Batteries
Silvestri, L., Paolone, A., Cirrincione, L., Stallworth, P. E., Greenbaum, S., Panero, S., Brutti, S., & Reale, P. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0761706jes · Cited by 16
Xia, G., Chen, J., Sun, W., Tan, Y., Guo, Z., Liu, H., & Yu, X. (2014) · Nanoscale · doi:10.1039/c4nr03257h · Cited by 16
Enhanced dehydrogenation performance of LiBH4 by confinement in porous NiMnO3 microspheres
Xu, X., Zang, L., Zhao, Y., Liu, Y., Wang, Y., & Jiao, L. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.08.088 · Cited by 16
Krebsz, M., Pasinszki, T., Sreenath, S., & Ting, V. P. (2025) · EES Catalysis · doi:10.1039/d5ey00134j · Cited by 14
Novel materials and technologies for hydrogen storage
Ismail, M., Yahya, M. S., Idris, N. H., Mustafa, N. S., & Yap, M. F. A. A. H. (2020) · Elsevier eBooks · doi:10.1016/b978-0-12-819553-6.00014-3 · Cited by 14
Hanlon, J., Reardon, H., Tapia‐Ruiz, N., & Gregory, D. H. (2012) · Australian Journal of Chemistry · doi:10.1071/ch11437 · Cited by 14
Yu, H., Yuan, Z., Han, Q., Li, J., & Li, T. (2026) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2026.153673 · Cited by 12
Wahab, M. A., Karim, M. R., Al‐Mubaddel, F. S., Alnaser, I. A., Will, G. D., & Abdala, A. A. (2023) · Journal of Energy Storage · doi:10.1016/j.est.2023.109206 · Cited by 11
Direct synthesis and dehydrogenation properties of NaAlH 4 catalyzed with ball‐milled Ti–B
Li, L., Zhang, Z., Wang, Y., Jiao, L., & Yuan, H. (2016) · Rare Metals · doi:10.1007/s12598-016-0772-x · Cited by 11
Javadian, P., Nielsen, T. K., Ravnsbæk, D. B., Jepsen, L. H., Polański, M., Płociński, T., Kunce, I., Besenbacher, F., Bystrzycki, J., & Jensen, T. R. (2015) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2015.08.035 · Cited by 11
Self-citationBehavior of decomposed ammonia borane at high pressure
Sun, Y., Chen, J., Drozd, V., Najiba, S., & Bollinger, C. (2014) · Journal of Physics and Chemistry of Solids · doi:10.1016/j.jpcs.2014.12.004 · Cited by 11
Nanostructured and Complex Hydrides for Hydrogen Storage
Jepsen, L. H., Paskevicius, M., & Jensen, T. R. (2017) · Wiley eBooks · doi:10.1002/9783527696109.ch18 · Cited by 11
Self-citationArora, E., Saini, S., Basera, P., Kumar, M., Singh, A., & Bhattacharya, S. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b08687 · Cited by 10
Metadata
- Authors
- Nielsen, T. K., Polanski, M., Zasada, D., Javadian, P., Besenbacher, F., Bystrzycki, J., Skibsted, J., & Jensen, T. R.
- Affiliations
- Aarhus University (DK)
- Faculty of Advanced Technology and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland
- Military University of Technology in Warsaw (PL)
- Corresponding author
- Jensen, Torben R.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-05
- Volume
- 5
- Issue
- 5
- Pages
- 4056-4064
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2040357673
- Cited by
- 117
- References
- 43
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 2 · 2023: 6 · 2022: 5 · 2021: 8 · 2020: 7 · 2019: 1 · 2018: 10 · 2017: 12 · 2016: 10 · 2015: 9 · 2014: 10 · 2013: 12 · 2012: 15
- FWCI
- 6.59
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Nano (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Physical Sciences › Materials Science › Materials Chemistry › Energetic Materials and Combustion
- Physical Sciences › Materials Science › Metals and Alloys › Hydrogen embrittlement and corrosion behaviors in metals
- Keywords
- sodium alanate, NaAlH4, hydrogen storage, hydrogen desorption kinetics, catalysts, nanoconfinement, carbon aerogels, resorcinol-formaldehyde, melt infiltration, synergistic effect, hydrogen release rate
- MeSH terms
- Absorption, Chlorine, Hydrogen, Kinetics, Materials Testing, Particle Size, Titanium, Nanostructures
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
