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Cited by 265

The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.

Predicting Nanocrystal Shape through Consideration of Surface-Ligand Interactions

Bealing, Clive R., Baumgardner, William J., Choi, Joshua J., Hanrath, Tobias, Hennig, Richard G.·2012·ACS Nano
DOI 10.1021/nn3000466
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Abstract

Density functional calculations for the binding energy of oleic acid-based ligands on Pb-rich {100} and {111} facets of PbSe nanocrystals determine the surface energies as a function of ligand coverage. Oleic acid is expected to bind to the nanocrystal surface in the form of lead oleate. The Wulff construction predicts the thermodynamic equilibrium shape of the PbSe nanocrystals. The equilibrium shape is a function of the ligand surface coverage, which can be controlled by changing the concentration of oleic acid during synthesis. The different binding energy of the ligand on the {100} and {111} facets results in different equilibrium ligand coverages on the facets, and a transition in the equilibrium shape from octahedral to cubic is predicted when increasing the ligand concentration during synthesis.

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Metadata

Authors
Bealing, C. R., Baumgardner, W. J., Choi, J. J., Hanrath, T., & Hennig, R. G.
Venue
ACS Nano
Publisher
American Chemical Society (ACS)
Published
2012-02-29
Volume
6
Issue
3
Pages
2118-2127
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
DOI
10.1021/nn3000466
OpenAlex
W2325322700
Cited by
265
References
52
FWCI
10.57
Type
journal article
Language
en
Open access
closed

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