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Effects of Surface Chemistry on the Generation of Reactive Oxygen Species by Copper Nanoparticles
Open accessAbstract
Mercaptocarboxylic acids with different carbon chain lengths were used for stabilizing uniform 15 nm copper nanoparticles. The effects of surface chemistry such as ligand type and surface oxidation on the reactive oxygen species (ROS) generated by the copper nanoparticles were examined. Transmission electron microscopy (TEM), powder X-ray diffraction (PXRD), UV-vis spectroscopy, and an acellular ROS assay show that ROS generation is closely related to the surface oxidation of copper nanoparticles. It was found that the copper nanoparticles with longer chain ligands had surfaces that were better protected from oxidation and a corresponding lower ROS generating capacity than did particles with shorter chain ligands. Conversely, the copper nanoparticles with greater surface oxidation also had higher ROS generating capacity.
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Gillespie, P. A., Kang, G. S., Elder, A., Gelein, R., Chen, L., Moreira, A. L., Koberstein, J., Tchou-Wong, K.-M., Gordon, T., & Chen, L. C. (2010) · Nanotoxicology · doi:10.3109/17435390903470101 · Cited by 70
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Reactive oxygen species generating systems meeting challenges of photodynamic cancer therapy
Zhou, Z., Song, J., Nie, L., & Chen, X. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00271d · Cited by 2,098
Devaraj, M., Saravanan, R., Deivasigamani, R., Gupta, V. K., Gracia, F., & Jayadevan, S. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.06.028 · Cited by 382
Metadata
- Authors
- Shi, M., Kwon, H. S., Peng, Z., Elder, A., & Yang, H.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-05
- Volume
- 6
- Issue
- 3
- Pages
- 2157-2164
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2045095022
- Cited by
- 175
- References
- 1
- FWCI
- 4.78
- Type
- journal article
- Language
- en
- Open access
- green
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- Shi, M., Kwon, H. S., Peng, Z., Elder, A., & Yang, H. (2012). Effects of Surface Chemistry on the Generation of Reactive Oxygen Species by Copper Nanoparticles. ACS Nano. https://doi.org/10.1021/nn300445d
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