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Formation Mechanism of Colloidal Silver Nanoparticles: Analogies and Differences to the Growth of Gold Nanoparticles
Abstract
The formation mechanisms of silver nanoparticles using aqueous silver perchlorate solutions as precursors and sodium borohydride as reducing agent were investigated based on time-resolved in situ experiments. This contribution addresses two important issues in colloidal science: (i) differences and analogies between growth processes of different metals such as gold and silver and (ii) the influence of a steric stabilizing agent on the growth process. The results reveal that a growth due to coalescence is a fundamental growth principle if the monomer-supplying chemical reaction is faster than the actual particle formation.
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Citations
Cites
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols
LaMer, V. K., & Dinegar, R. H. (1950) · Journal of the American Chemical Society · doi:10.1021/ja01167a001 · Cited by 3,894
Cited by
Mechanisms of Nucleation and Growth of Nanoparticles in Solution
Thanh, N. T. K., Maclean, N., & Mahiddine, S. (2014) · Chemical Reviews · doi:10.1021/cr400544s · Cited by 3,399
Fundamental growth principles of colloidal metal nanoparticles – a new perspective
Polte, J. (2015) · CrystEngComm · doi:10.1039/c5ce01014d · Cited by 746
Self-citationSurface diffusion-limited lifetime of silver and copper nanofilaments in resistive switching devices
Wang, W., Wang, M., Ambrosi, E., Bricalli, A., Laudato, M., Sun, Z., Chen, X., & Ielmini, D. (2019) · Nature Communications · doi:10.1038/s41467-018-07979-0 · Cited by 328
Hendel, T., Wuithschick, M., Kettemann, F., Birnbaum, A., Rademann, K., & Polte, J. (2014) · Analytical Chemistry · doi:10.1021/ac502053s · Cited by 235
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Metadata
- Authors
- Polte, J., Tuaev, X., Wuithschick, M., Fischer, A., Thuenemann, A. F., Rademann, K., Kraehnert, R., & Emmerling, F.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-26
- Volume
- 6
- Issue
- 7
- Pages
- 5791-5802
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2025968484
- Cited by
- 253
- References
- 1
- FWCI
- 6.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Polte, J., Tuaev, X., Wuithschick, M., Fischer, A., Thuenemann, A. F., Rademann, K., Kraehnert, R., & Emmerling, F. (2012). Formation Mechanism of Colloidal Silver Nanoparticles: Analogies and Differences to the Growth of Gold Nanoparticles. ACS Nano. https://doi.org/10.1021/nn301724z
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.