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Patchy Nanocapsules of Poly(vinylferrocene)-Based Block Copolymers for Redox-Responsive Release

Staff, Roland H., Gallei, Markus, Mazurowski, Markus, Rehahn, Matthias, Berger, Rüdiger, Landfester, Katharina, Crespy, Daniel·2012·ACS Nano

Abstract

Nanocapsules composed of a poly(vinylferrocene)-block-poly(methyl methacrylate) shell and a hydrophobic liquid core are prepared in water. The nanocapsule shells display a patchy structure with poly(vinylferrocene) patches with sizes of 25 ± 3 nm surrounded by poly(methyl methacrylate). The functional nanopatches can be selectively oxidized, thereby influencing the colloidal morphology and introducing polar domains in the nanocapsule shell. The hydrophobic to hydrophilic transition in the redox-responsive nanopatches can be advantageously used to release a hydrophobic payload encapsulated in the core by an oxidation reaction.

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Metadata

Authors
Staff, R. H., Gallei, M., Mazurowski, M., Rehahn, M., Berger, R., Landfester, K., & Crespy, D.
Venue
ACS Nano
Published
2012-10-05
Volume
6
Issue
10
Pages
9042-9049
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2035092706
Cited by
194
References
0
FWCI
7.94
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Patchy Nanocapsules of Poly(vinylferrocene)-Based Block Copolymers for Redox-Responsive Release. https://app.cochat.ai/papers/10.1021/nn3031589
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Staff, R. H., Gallei, M., Mazurowski, M., Rehahn, M., Berger, R., Landfester, K., & Crespy, D. (2012). Patchy Nanocapsules of Poly(vinylferrocene)-Based Block Copolymers for Redox-Responsive Release. ACS Nano. https://doi.org/10.1021/nn3031589

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